Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Iron easily loses its phlogiston by the action of fire. The calx
that remains after its calcination is exceeding red; which makes
this be thought the natural colour of the earth of that metal. It
hath accordingly been observed, that all the earths and stones which
either are naturally red, or acquire that colour by calcination, are
ferruginous.
The yellowish red colour which every calx of Iron hath, in whatever
manner it be prepared, hath procured the name of _Crocus_ or _Saffron_
to every preparation of this kind. That made in the manner above
directed is called in Medicine _Crocus Martis astringens_.
The rust produced on the surface of Iron is a sort of calx of Iron made
by way of dissolution. The moisture of the air acts upon the metal,
dissolves it, and robs it of some of its phlogiston. This rust is
called in Medicine _Crocus Martis Aperiens_; because it is thought that
the saline parts, by means whereof the humidity dissolves the Iron,
remain united with the metal after its dissolution, and give it an
aperitive virtue. The Apothecaries prepare this sort of Saffron of Mars
by exposing Iron filings to the dew, till they be turned entirely to
rust: which is then called _Saffron of Mars by dew_.
Another Saffron of Mars is also prepared in a much shorter manner, by
mixing filings of Iron with pulverized Sulphur, and moistening the
mixture, which after some time ferments and grows hot. It is then set
on the fire; the Sulphur burns away, and the mass is kept stirring till
it become a red matter. This Saffron is nothing but Iron dissolved by
the Acid of Sulphur, which is known to be of the same nature with that
of Vitriol; and consequently this Saffron of Mars is no way differing
from Vitriol calcined to redness.
PROCESS V.
_Iron dissolved by the mineral Acids._
Put any mineral Acid whatever into a matrass with some water; set the
matrass on a sand-bath gently heated; drop into the vessel some filings
of Iron: the phenomena which usually accompany metalline dissolutions
will immediately appear. Add more filings, till you observe the Acid
hath lost all sensible action upon them: then remove your matrass from
the sand-bath; you will find in it a solution of Iron.
_OBSERVATIONS._
Iron is very easily dissolved by all the Acids. If you make use of the
Vitriolic Acid, care must be taken to weaken it with water, in case it
be concentrated; because the dissolution will succeed the better. The
vapours that rise on this occasion are inflammable; and if a lighted
paper be held to the mouth of the matrass, especially after keeping
it stopt for some time and shaking the whole gently, the sulphureous
vapours take fire with such rapidity as to produce a considerable
explosion; which is sometimes strong enough to burst the vessel into a
thousand pieces. This solution hath a green colour, and is in fact a
fluid Green Vitriol, which wants nothing but rest to make it shoot into
crystals.
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