Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
All Tin ores contain a considerable quantity of Arsenic, and no Sulphur
at all, or at most very little. Hence it comes that, though Tin be the
lightest of all metals, its ore is nevertheless much heavier than any
other; Arsenic being much heavier than Sulphur, of which the ores of
every other kind always contain a pretty large proportion. This ore is
moreover very hard, and is not brought to a fine powder with so much
ease as the rest.
These properties of Tin ore furnish us with the means of separating it
easily by lotion, not only from earthy and stony parts, but even from
the other ores which may be mixed with it. And this is of the greater
advantage on two accounts, _viz._ because Tin cannot endure, without
the destruction of a great part thereof, the degree of fire necessary
to scorify the refractory matters which accompany its ore; and again
because this metal unites so easily with Iron and Copper, the ores
of which are pretty commonly blended with Tin ore, that, after the
reduction, it would be found adulterated with a mixture of these two
metals, if they were not separated from it before the fusion.
But sometimes the Iron ore confounded with that of Tin is very heavy,
and is not easily pulverized; whence it comes to pass that it cannot be
separated therefrom by washing only. In that case the magnet must be
employed to separate it, after the ore hath been roasted.
Roasting is moreover necessary for Tin ore, in order to dissipate the
Arsenic which volatilizes, calcines, or destroys one part of the Tin,
and reduces the rest to a short, brittle substance, like a Semi-metal.
The ore is known to be sufficiently roasted when no more fumes rise
from it; when it has lost the smell of garlic; and when it does not
whiten a clean plate of Iron held over it.
Tin being one of those metals which are most easily calcined, it is
necessary in reducing its ore to employ such matters as may furnish it
with phlogiston. In order to defend it from the contact of the air,
which always accelerates the calcination of metallic substances, the
mixture is to be covered with Sea salt; and the addition of pitch helps
to increase the quantity of phlogiston.
PROCESS II.
_The Calcination of Tin._
Into an unglazed earthen dish put the quantity of Tin you intend to
calcine; melt it, and keep stirring it from time to time. Its surface
will be covered with a greyish white powder: continue the calcination
till all your Tin be converted into such a powder, which is the _Calx
of Tin_.
_OBSERVATIONS._
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