Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When this apparatus is dry, put your mixed mass of Copper and Lead into
the upper vessel: both in that, and in the other vessel, light a very
gentle fire of wood or charcoal, so as not to exceed the degree of heat
necessary to melt Lead. In such a degree of heat the Lead contained
in the mixed mass will melt, and you will see it run out of the upper
vessel into the lower; at the bottom of which it will unite into a
Regulus. When in this degree of heat no more Lead flows, increase the
fire a little, so as to make the vessel moderately red.
When no more will run, collect the Lead contained in the lower vessel.
Melt it over again in an iron ladle, with a degree of fire sufficient
to make the ladle red; throw into it a little tallow or pitch, and
while it burns keep stirring the metal, in order to reduce any part of
it that may be calcined. Remove the pellicle or thin crust which will
form on the surface; squeeze out all the Lead it contains, and then put
it to the mass of Copper left in the upper vessel. Check the fire, and
in the same manner take off a second skin that will form on the surface
of the Lead. Lastly, when the metal is ready to fix, take off the skin
that will then appear on it. The Lead remaining after this will be very
pure, and free from all alloy of Copper.
With regard to the Copper itself, you will find it in the upper vessel
covered with a thin coat of Lead: and if the Lead mixed with it was in
the proportion of a fourth or a fifth part only, and the fire applied
was gentle and slow, it will retain nearly the same form after the
operation that the mixed mass had before.
_OBSERVATIONS._
Lead frequently remains mixed with Copper after the reduction of its
ore, especially if the ore was pyritose. Though Copper be a much more
beautiful and more ductile metal than Lead, yet the latter by being
alloyed with the former is rendered eager and brittle. This bad quality
is easily discovered by the eye on breaking it: for the surface of
the broken part appears all granulated; whereas when it is pure it is
more evenly, and resembles a congeries of solid angles. If the Lead
be alloyed with a considerable quantity of Copper, its colour hath a
yellowish cast.
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