Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Considering the bad qualities which Copper communicates to Lead, it
is necessary to separate these two metals from each other. The method
above laid down is the simplest and the best. It is founded on two
properties belonging to Lead: the first is that of being much more
fusible than Copper; so that it will melt and run in a degree of heat
that is not capable of making the Copper even red-hot, which yet is
very far from being able to melt it: the second is, that Lead, though
it hath an affinity with Copper, and unites very perfectly therewith,
yet is not able to dissolve it without a greater heat than the degree
barely necessary to fuse Lead. Hence it comes that Lead may be melted
in a Copper vessel, provided no greater degree of heat be applied than
that purpose requires. But when the Lead becomes so hot as to be red,
fume, and boil, it instantly begins to dissolve the Copper. For this
reason, it is essential to the success of our operation that a moderate
degree of heat only be applied, and no greater than is requisite to
keep the Lead in fusion.
Charcoal-dust is made an ingredient in the composition of the vessels
used on this occasion, in order to prevent the calcination of the Lead.
The iron plate, with which the entrance of the gutter within the upper
vessel is narrowed, serves to prevent the larger pieces of Copper,
which the Lead may carry along with it, from passing through: it stops
them, and allows the Lead to run off alone.
But as these parcels of Copper may entirely choak the passage, care
must be taken, when any happen to be stopt, to remove them from the
entrance of the gutter, and push them back into the middle of the
vessel. It is also necessary to observe whether or no the Lead fixes
any where in the passage; and, if it does, the heat of that part must
be increased, in order to melt it and make it run off.
Notwithstanding all the precautions that can be taken, to hinder the
melted Lead from carrying off any Copper with it, it is impossible to
prevent this inconvenience entirely; and therefore the Lead is melted
over again, in order to separate the small portion of Copper with which
it is still adulterated.
As Copper is much lighter than Lead, if these two metals happen to
be so blended together that the Copper, without being in fusion and
dissolved by the Lead, is only interposed between the parts of the
melted Lead, so as to swim therein, it is then precisely in the case of
a solid body plunged into a fluid heavier than itself, and must rise
to the surface, like wood thrown into water. It is proper to burn some
inflammable matter on this melted Lead, in order to reduce such parts
thereof as are constantly calcining on its surface while it is in
fusion; for without this precaution they would be taken off together
with the Copper.
Public-domain text, read in full here on John Shaqi.
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