Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
To account for this phenomenon Natural Philosophers and Chymists have
invented several ingenious hypotheses, but none of them entirely
satisfactory. As we have no established theory to proceed upon, we
shall not undertake to explain this extraordinary fact.
PROCESS IV.
_To prepare Glass of Lead._
Take two parts of Litharge, and one part of pure crystalline Sand;
mingle them together as exactly as possible, adding a little Nitre and
Sea-salt: put this mixture into a crucible of the most solid and most
compact earth. Shut the crucible with a cover that may perfectly close
it.
Set the crucible thus prepared in a melting furnace; fill the furnace
with coals; light the fire gradually, so that the whole may be slowly
heated: then raise the fire so as to make the crucible very red, and
bring the matter it contains into fusion; keep it thus melted for a
quarter of an hour.
Then take the crucible out of the furnace, and break it: in the bottom
thereof you will most commonly find a small button of Lead, and over
it a transparent Glass, of a yellow colour nearly resembling that of
amber. Separate this Glass from the little button of metal, and from
the saline matters which you will find above it.
_OBSERVATIONS._
Pure Lead, being exposed to a strong fire without any additament,
turns to Litharge; which is a scaly sort of substance, more or less
yellowish, shining, and soft to the touch. This is the first advance
to the Vitrification of Lead. The large refineries of Gold and Silver
by the means of Lead furnish a great quantity of this material. It is
sometimes whitish, and is then called _Litharge of Silver_; sometimes
yellow, and then bears the name of _Litharge of Gold_. The difference
of its colour depends on the degree of fire it hath undergone, and on
the metalline substances vitrified with it.
Litharge alone is very fusible, and being exposed to the fire is easily
converted into glass: but this Glass of Lead, made without additament,
is so active, so penetrating, and so apt to swell, that it can scarcely
be made use of when pure. We are obliged in some sort to clog it, by
uniting it with some vitrifiable matter that is not so subtile, such
as sand; and it is for this reason, not to render the mixture more
fusible, that we have directed the addition of one third part of Sand
to two thirds of Litharge.
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