Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The Nitre and Sea-salt, prescribed as ingredients in the mixture, are
designed to procure an equal fusion of the whole. For, as the sand is
lighter and less fusible than the Litharge, it will partly rise towards
the upper part of the crucible when that matter first begins to flow;
in consequence whereof the contents of the upper part will be much more
difficult to melt, and form a Glass much more compact than that below:
but the Nitre and Sea-salt possessing the upper part of the crucible,
because they are still lighter than the Sand, and being in their own
nature very efficacious fluxes, on account of their great fusibility,
they quickly bring about the fusion of those particles of sand, which,
having escaped the action of the Litharge, may have risen unvitrified
to its surface.
The most difficult thing to procure, and yet the most necessary to the
success of this operation, is a crucible of earth so firm and compact
as not to be penetrated by the Glass of Lead, which corrodes and makes
its way through every thing.
The precaution of chusing a crucible, that shall contain a good deal
more than the matter to be vitrified, is a necessary one, because
Litharge and Glass of Lead are very apt to swell.
The rule to keep the crucible close shut is also indispensably
necessary, to prevent any bit of charcoal, or other inflammable matter,
from falling into it: for when this happens it occasions a reduction of
the Lead, which is always attended with a sort of effervescence, and
such a considerable heaving, that commonly most of the mixture runs
over the crucible. For the same reason it is very proper, before you
expose the mixture to the fire, to examine whether or no it contains
any matter capable of furnishing a phlogiston during the operation; and
if it does, to remove that matter with great care.
The little button of Lead, found at the bottom of the crucible after
the operation, comes from a small portion of Lead that is commonly
left in Litharge, unless you prepare it carefully yourself, and do not
take it from the fire till you are sure of having destroyed all the
Lead. Besides, this small portion of Lead can be of no prejudice to the
operation, because it cannot communicate its phlogiston to the rest of
the matter.
The revivifying of Litharge, of the Calx, and of the Glass of Lead, may
be obtained by the same processes as the reduction of its ore.
PROCESS V.
_Lead dissolved by the Nitrous Acid._
Put into a matrass some _aqua fortis_ precipitated like that used to
dissolve Silver; weaken it by mixing therewith an equal quantity of
common water; set the matrass in a hot sand-bath; throw into it, little
by little, small bits of Lead, till you see that no more will dissolve.
_Aqua fortis_ thus lowered will dissolve about a fourth of its weight
of Lead.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account