Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Sea-salt, or Spirit of Salt, separates the Lead from its solvent, and
precipitates it, as we observed before, into a _Plumbum corneum_: but
this precipitate differs from the _Luna cornea_, as being very soluble
in water; whereas the _Luna cornea_ will not dissolve in it at all;
or at least dissolves therein with great difficulty, and in a very
small quantity. This _Plumbum corneum_ dissolved in water is again
precipitated by the Vitriolic Acid. M. Grosse observes, that this
forms an exception to the eighth column of Mr. Geoffroy's Table of
Affinities; in which the Acid of Sea-salt is marked as having a greater
affinity than any other Acid with Metallic substances.
Our solution of Lead is also precipitated in a white powder by several
Neutral Salts; such as Vitriolated Tartar, Alum, and common Vitriol. It
is by the means of double affinities that these Neutral Salts effect
this precipitation.
Even pure water alone is capable of precipitating the Lead of our
solution, by weakening the Acid, and thereby disabling it from keeping
the metal suspended.
Lastly, as all the solutions of metals in Acids are nothing but
Neutral Metallic Salts in a fluid form, so if the solution of Lead be
evaporated over the fire, it will shoot into very beautiful crystals,
about the bigness of hemp-seed, shaped like regular pyramids having
square bases. These crystals are yellowish, and have a sweet saccharine
taste: but what is most singular in them is, that, as they consist of
the Nitrous Acid combined with Lead, which manifestly contains a great
deal of phlogiston, they constitute a Nitrous Metallic Salt, which has
the property of deflagrating in a crucible, without the addition of any
other inflammable matter. It is extremely hard to dissolve this Salt in
water.
The grey mercurial precipitate which whitens Gold, and in which little
globules of running Mercury are perceivable, is far from being pure
Mercury. This metallic substance makes but a small part thereof: for
it is an assemblage, 1. of little crystals of the same nature with
those afforded by the evaporated solution; 2. of a portion of the white
matter, or powder, which renders the solution milky; 3. of a grey
powder, which M. Grosse considers as the only mercurial part; 4. and
lastly, of little particles of Lead that have escaped the action of the
solvent; especially if a little more Lead than the Acid is capable of
dissolving were added with a view to saturate it entirely, as in the
present process.
By means of motion and heat the small parcels of Mercury may be
amalgamated with the Lead.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account