Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
There is gradually formed upon the Lead, as it dissolves, first a
grey powder, and afterwards a white crust, which at last hinder the
solvent from acting on the remaining part of the metal; and therefore
the liquor should be made to boil, and the vessel should be shaken to
remove those impediments, by which means all the Lead will be dissolved.
_OBSERVATIONS._
Lead very much resembles Silver, with respect to the phenomena which
attend its dissolution in Acids. For example, the Nitrous Acid must
be very pure and uncontaminated with the Vitriolic or Marine Acid, to
qualify it for keeping the Lead in solution: for, if it be mixed with
either the one or the other of these Acids, the Lead will precipitate
in the form of a white powder as fast as it dissolves; which is just
the case with Silver.
If the Vitriolic Acid be mixed with the Nitrous, the precipitate will
be a combination of the Vitriolic Acid with Lead; that is, a Neutral
Metallic Salt, or Vitriol of Lead. If the Acid of Sea-salt be mixed
therewith, the precipitate will be a _Plumbum corneum_; that is, a
Metallic Salt resembling the _Luna cornea_.
When all the Lead is dissolved as above described, the liquor appears
milky. If it be kept warm over the fire till little crystals begin to
appear on its surface, and afterwards left to stand quiet, in a certain
time there will be found at the bottom a greyish powder, which being
tried on Gold is Mercurial enough to whiten it. Little globules of
Quick-silver are even discernible in it.
We owe this observation, together with this manner of proving the
existence of Mercury in Lead, and of procuring it from thence, to M.
Grosse, who hath given an account of his process in the Memoirs of the
Academy of Sciences, from whence we have copied the description of the
operation in hand.
The solution being quickly poured off by inclination from the grey
mercurial precipitate is still milky, and deposites another white
sediment. When this second precipitate falls the liquor becomes clear
and limpid, and is then of a fine yellow colour, like a solution of
Gold. On this gold-coloured solution, and on the two precipitates
above-mentioned, M. Grosse made several observations, the chief of
which we shall here insert.
The yellow liquor affects the tongue at first with a taste of
sweetness; but afterwards vellicates it very smartly, and leaves on it
a strong sensation of acrimony, which continues for a long time.
Alkalis precipitate the Lead suspended in this liquor, just as they do
all other metals dissolved by Acids; and this precipitate of Lead is
white.
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