Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The Vitriolic Acid dissolves Mercury pretty well: but for this purpose
the Acid must be very hot, or even boil; and then too it is a very
long time before the dissolution is completed. We have directed the
operation to be performed in a retort; because this solution is usually
employed to make another preparation called _Turbith Mineral_, which
requires that as much as possible of the Acid solvent be abstracted by
distillation. Having therefore dissolved your Mercury in the Vitriolic
Acid, if you will now prepare the Turbith, you must, by continuing
to heat the retort, drive over all the liquor into the receiver, and
distil till nothing remains but a white powdery matter: then break
the retort; pulverize its contents in a glass mortar, and thereon
pour common water, which will immediately turn the white matter of a
lemon-colour; wash this yellow matter in five or six warm waters, and
it will be what is called in medicine _Turbith Mineral_; that is, a
combination of the Vitriolic Acid with Mercury, five or six grains
whereof is a violent purgative, and also an emetic; qualities which
it possesses in common with the Vegetable Turbith, whose name it hath
therefore taken.
There rises out of the retort, both while the Mercury is dissolving,
and while the solvent is abstracting, a weak Spirit of Vitriol; because
a great part of the Acid remains united with the Quick-silver, which
at last appears in the form of a white powder: so that, if you do not
incline to save the Acid which rises on this occasion, you may, instead
of drawing off the liquor in a retort, evaporate it in a glass bason
set on a sand-bath, which will be much sooner done.
It is very remarkable that, on this occasion, the Mercury may be
exposed, without any danger of subliming, to a much greater heat than
it is capable of bearing when not combined with the Vitriolic Acid;
which shews that this Acid hath the property of fixing Mercury to a
certain degree.
The white matter, that remains after the evaporation of the fluid, is
one of the most violent corrosives, and would prove an actual poison if
taken internally. By washing it several times in warm water it is freed
from a great deal of its Acid, and so considerably sweetened. The proof
is this; if the water used in washing the Turbith be evaporated, there
remains after the evaporation a matter in form of a Salt, that being
set in a cellar runs into a liquor called _Oil of Mercury_, which is a
powerful corrosive. Several authors further direct Spirit of Wine to be
burnt on the Turbith, to sweeten it still more.
Public-domain text, read in full here on John Shaqi.
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