Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
That neutral salt mentioned above, which is formed by combining the
Marine Acid with a common fixed Alkali, and called _Sal febrifugum
Sylvii_, hath also this property.
India furnishes us with a saline substance, known by the name of
_Borax_, which flows very easily, and then takes the form of glass. It
is of great use in facilitating the fusion of metallic substances. It
possesses some of the properties of fixed Alkalis, which has induced
certain Chymists to represent it, through mistake, as a pure fixed
Alkali.
By mixing borax with the vitriolic Acid, Mr. Homberg obtained from
it a salt, which sublimes in a certain degree of heat, whenever such
a mixture is made. This salt has very singular properties; but its
nature is not yet thoroughly understood. It dissolves in water with
great difficulty; it is not volatile, though it rises by sublimation
from the borax. According to Mr. Rouelle's observation, it rises then
only by means of the water which carries it up: for, when once made,
it abides the fiercest fire, flows and vitrifies just as borax does:
provided care be taken to free it previously from moisture by drying
it properly. Mr. Homberg called it _Sedative Salt_, on account of its
medical effects. The sedative salt hath the appearance, and some of the
properties, of a neutral salt; for it shoots into crystals, and does
not change the colour of violets; but it acts the part of an Acid with
regard to Alkalis, uniting with them to the point of saturation, and
thereby forming a true neutral salt. It also acts, like the Acid of
vitriol on all neutral salts; that is, it discharges the Acid of such
as have not the vitriolic Acid in their composition.
Since Mr. Homberg's time it hath been discovered, that a sedative salt
may be made either with the nitrous or with the marine Acid; and that
sublimation is not necessary to extract it from the borax, but that it
may be obtained by crystallization only. For this latter discovery we
are indebted to Mr. Geoffry, as we are to Mr. Lemery for the former.
Since that time M. Baron d'Henouville, an able Chymist, hath shewn that
a sedative salt may be obtained by the means of vegetable Acids; and
hath lately demonstrated, in some excellent papers published in the
collection of Memoirs written by the correspondents of the Academy of
Sciences, that the sedative salt exists actually and perfectly in the
borax, and that it is not produced by mixing Acids with that saline
substance, as it seems all the Chymists before him imagined. This he
proves convincingly from his analysis of borax, (which thereby appears
to be nothing else but the sedative salt united with that fixed Alkali
which is the basis of Sea-salt) and from his regenerating the same
borax by uniting together that Alkali and the sedative salt: a proof
the most complete that can possibly be produced in natural philosophy,
and equivalent to demonstration itself.
Public-domain text, read in full here on John Shaqi.
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