Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The rust of Copper is always green or blue, or of a colour between
these two. Internally used it is very noxious, being a real poison, as
are all the solutions of this metal made by any acid whatever. The blue
colour which Copper constantly assumes, when corroded by any saline
substance, is a sure sign by which it may be discovered wherever it
exists, even in a very small quantity.
Copper dissolved in the vitriolic acid forms a kind of metalline salt,
which shoots into rhomboidal crystals of a most beautiful blue colour.
These crystals are called _Blue Vitriol_, or _Vitriol of Copper_. They
are sometimes found ready formed in the bowels of the earth; and may
be artificially made by dissolving Copper in the vitriolic acid; but
the solution will not succeed unless the acid be well dephlegmated.
The taste of this vitriol is saltish and astringent. It retains a
considerable quantity of water in crystallizing, on which account it is
easily rendered fluid by fire.
It must be observed, that, when it is exposed to a certain degree of
heat, in order to free it of its humidity, a great part of its acid
flies off at the same time: and hence it is that, after calcination,
there remains only a kind of earth, or metalline calx, of a red colour,
which contains but very little acid. This earth cannot be brought to
flow but with the greatest difficulty.
A solution of Copper in the nitrous acid forms a salt which does not
crystallize, but, when dried, powerfully attracts the moisture of the
air. The same thing happens when it is dissolved in the spirit of salt,
or in _aqua regis_.
If the Copper thus dissolved by any of these acids be precipitated
by an earth or an alkali, it retains nearly the colour it had in the
solution: but these precipitates are scarce any thing more than the
earth of Copper, or Copper deprived of most of its phlogiston; so that
if they were exposed to a violent fire, without any additament, a great
part of them would be converted into an earth that could never be
reduced to a metalline form. Therefore, when we intend to reduce these
precipitates to Copper, it is necessary to add a certain quantity of a
substance capable of restoring to them the phlogiston they have lost.
The substance which hath been found fittest for such reductions is
charcoal-dust; because charcoal is nothing but a phlogiston closely
combined with an earth, which renders it exceedingly fixed, and capable
of resisting a violent force of fire. But as charcoal will not melt,
and consequently is capable of preventing rather than forwarding the
flux of a metalline calx or glass, which nevertheless is essentially
necessary to complete the reduction, it hath been contrived to mix
it, or any other substance containing the phlogiston, with such fixed
alkalis as easily flow, and are fit to promote the flux of other
bodies. These mixtures are called _Reducing Fluxes_; because the
general name of _Fluxes_ is given to all salts or mixtures of salts,
which facilitate fusion.
Public-domain text, read in full here on John Shaqi.
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