Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
If Sulphur be applied to Copper made perfectly red-hot, the metal
immediately runs; and these two substances uniting form a new compound
much more fusible than pure Copper.
This compound is destroyed by the sole force of fire, for two reasons:
the first is, that, sulphur being volatile, the fire is capable
of subliming a great part of it, especially when it is in a great
proportion to the Copper with which it is joined; the second is, that
the portion of sulphur which remains, being more intimately united with
the Copper, though it be rendered less combustible by that union, is
nevertheless burnt and consumed in time. Copper being combined with
sulphur, and together with it exposed to the force of fire, is found
to be partly changed into a blue vitriol; because the vitriolic acid,
being disengaged by burning the sulphur, is by that means qualified to
dissolve the Copper. The affinity of Copper with sulphur is greater
than that of Silver.
This metal, as well as the other imperfect metals and the semi-metals,
being mingled with nitre and exposed to the fire, is decomposed and
calcined much sooner than by itself; because the phlogiston which it
contains occasions the deflagration of the nitre, and consequently
the two substances mutually decompose each other. There are certain
metalline substances whose phlogiston is so abundant, and so weakly
connected with their earth, that when they are thus treated with nitre,
there arises immediately a detonation, accompanied with flame, and as
violent as if sulphur or charcoal-dust had been employed; so that in a
moment the metalline substance loses its phlogiston, and is calcined.
The nitre, after these detonations, always assumes an alkaline
character.
SECTION IV.
_Of_ IRON.
Iron is lighter and less ductile than Copper; but it is much harder,
and of more difficult fusion.
It is the only body that has the property of being attracted by the
magnet, which therefore serves to discover it wherever it is. But it
must be observed, that it hath this property only when in its metalline
state, and loses it when converted to an earth or calx. Hence very few
Iron-ores are attracted by the load-stone: because, for the most part,
they are only sorts of earths, which require a phlogiston to be added
before they can be brought to the form of true Iron.
When Iron hath undergone no other preparation but the fusion which is
necessary to smelt it from its ore, it is usually quite brittle, and
flies to pieces under the hammer: which arises in some measure from its
containing a certain portion of unmetallic earth interposed between its
parts. This we call _Pig Iron_.
By melting this a second time it is rendered purer, and more free from
heterogeneous matters: but still, as its proper parts are probably not
brought sufficiently near, or closely enough united, till the Iron hath
undergone some further preparation besides that of fusion, it seldom
hath any degree of malleability.
Public-domain text, read in full here on John Shaqi.
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