Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
All these preparations of Lead are greatly disposed to perfect fusion
and vitrification, and for that purpose require but a moderate degree
of fire; the calx or earth of Lead being of all metalline earths that
which vitrifies the most easily.
Lead hath not only the property of turning into glass with the greatest
facility, but it hath also that of promoting greatly the vitrification
of all the other imperfect metals; and, when it is actually vitrified,
procures the ready fusion of all earths and stones in general, even
those which are refractory, that is, which could not be fused without
its help.
Glass of Lead, besides its great fusibility, hath also the singular
property of being so subtile and active as to corrode and penetrate the
crucibles in which it is melted, unless they be of an earth that is
exceeding hard, compact, and withal very refractory: for Glass of Lead
being one of the most powerful fluxes that we know, if the earth of
the crucible in which it is melted be in the smallest degree fusible,
it will be immediately vitrified; especially if there be any metallic
matter in its composition.
The great activity of Glass of Lead may be weakened by joining it with
other vitrifiable matters: but unless these be added in a very great
proportion, it will still remain powerful enough to penetrate common
earths, and carry off the matters combined with it.
On these properties of Lead, and of the Glass of Lead, depends the
whole business of refining Gold and Silver. It hath been shewn, that as
these two metals are indestructible by fire, and the only ones which
have that advantage, they may be separated from the imperfect metals,
when mixed therewith, by exposing the compound to a degree of fire
sufficiently strong to vitrify the latter; which, when once converted
into glass, can no longer remain united with any metal that has its
metalline form. But it is very difficult to procure this vitrification
of the imperfect metals, when united with Gold and Silver; nay, it
is in a manner impossible to vitrify them entirely, for two reasons:
first, because most of them are naturally very difficult to vitrify;
secondly, because the union they have contracted with the perfect
metals defends them, in a manner, from the action of the fire, and that
so much the more effectually as the proportion of the perfect metals
is greater; which being indestructible, and in some sort coating over
those with which they are alloyed, serve them as a preservative and
impenetrable shield against the utmost violence of fire.
Public-domain text, read in full here on John Shaqi.
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