Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
It is therefore clear, that a great deal of labour may be saved, and
that Gold and Silver may be refined to a much greater degree of purity
than can otherwise be obtained, if to a mixture of these metals with
Copper, for instance, or any other imperfect metal be added a certain
quantity of Lead. For the Lead, by its known property, will infallibly
produce the desired vitrification; and as it likewise increases
the proportion of the imperfect metals, and so lessens that of the
perfect metals, in the mass, it evidently deprives the former of a
part of their guard, and so effects a more complete vitrification. In
conclusion, as the Glass of Lead hath the property of running through
the crucible, and carrying with it the matters which it has vitrified,
it follows, that, when the vitrification of the imperfect metals is
effected by its means, all those vitrified matters together penetrate
the vessel containing the fused metalline mass, disappear, and leave
only the Gold and Silver perfectly pure, and freed, as far as is
possible, from all admixture of heterogeneous parts.
The better to promote the separation of such parts it is usual to
employ, in this process, a particular sort of small crucibles, made of
the ashes of calcined bones, which are exceedingly porous and easily
pervaded. They are called _cupels_, on account of their figure, which
is that of a wide-mouthed cup: and from hence the operation takes its
name; for when we refine Gold and Silver in this manner we are said
to _cupel_ those metals. It is easy to perceive that the more Lead is
added the more accurately will the Gold and Silver be refined; and
that so much the more Lead ought to be added as the perfect metals are
alloyed with a greater proportion of the imperfect. This is the most
severe trial to which a perfect metal can be put; and consequently any
metal that stands it may be fairly considered as such.
In order to denote the fineness of Gold, it is supposed to be divided
into twenty-four parts called _carats_; and Gold which is quite pure
and free from all alloy is said to be twenty-four _carats fine_; that
which contains 1/24 part of alloy is called Gold of twenty-three
carats; that which contains 2/24 of alloy is but twenty-two carats; and
so on. Silver again is supposed to be divided into twelve parts only,
which are called _penny-weights_: so that when absolutely pure it is
said to be twelve _penny-weights fine_; when it contains 1/12 of alloy,
it is then called eleven penny-weights fine; when it contains 2/12 of
alloy, it is called ten penny-weights fine, and so on.
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