Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Mercury has the property of dissolving all the metals, Iron only
excepted. But it is a condition absolutely necessary to the success of
such dissolution, that the metalline substances be possessed of their
phlogiston; for if they be calcined, Mercury cannot touch them: and
hence it follows, that Mercury doth not unite with substances that are
purely earthy. Such a combination of a metal with Mercury is called an
_Amalgam_. Trituration alone is sufficient to effect it; however, a
proper degree of heat also is of use.
Mercury amalgamated with a metal gives it a consistence more or less
soft, and even fluid, according to the greater or smaller proportion of
Mercury employed. All amalgams are softened by heat, and hardened by
cold.
Mercury is very volatile; vastly more so than the most unfixed metals;
moreover, the union it contracts with any metal is not sufficiently
intimate to entitle the new compound resulting from that union to all
the properties of the two substances united: at least with regard to
their degree of fixity and volatility. From all which it follows, that
the best and surest method of separating it from metals dissolved by
it, is to expose the amalgam to a degree of heat sufficient to make
all the Quick-silver rise and evaporate; after which the metal remains
in the form of a powder, and being fused recovers its malleability.
If it be thought proper to save the Quick-silver, the operation must
be performed in close vessels, which will confine and collect the
mercurial vapours. This operation is most frequently employed to
separate Gold and Silver from the several sorts of earths and sands
with which they are mixed in the ore; because these two metals, Gold
especially, are of sufficient value to compensate the loss of Mercury,
which is inevitable in this process: besides, as they very readily
amalgamate with it, this way of separating them from every thing
unmetallic is very facile and commodious.
Mercury is dissolved by acids; but with circumstances peculiar to each
particular sort of acid.
The vitriolic acid, concentrated and made boiling hot, seizes on
it, and presently reduces it to a kind of white powder, which turns
yellow by the affusion of water, but does not dissolve in it; it is
called _Turbith Mineral_. However, the vitriolic acid on this occasion
unites with a great part of the Mercury, in such a manner that the
compound is soluble in water. For if to the water which was used to
wash the Turbith a fixed alkali be added, there falls instantly a
russet-coloured precipitate, which is no other than Mercury separated
from the vitriolic acid by the intervention of the alkali.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account