Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
This dissolution of Mercury by the vitriolic acid is accompanied with
a very remarkable phenomenon; which is, that the acid contracts a
strong smell of volatile spirit of sulphur: a notable proof that part
of the phlogiston of the Mercury hath united therewith. And yet, if the
Mercury be separated by means of a fixed alkali, it does not appear to
have suffered any alteration. Turbith mineral is not so volatile as
pure Mercury.
The nitrous acid dissolves Mercury with ease. The solution is limpid
and transparent, and as it grows cold shoots into crystals, which are a
nitrous mercurial salt.
If this solution be evaporated to dryness, the Mercury remains
impregnated with a little of the acid, under the form of a red powder,
which hath obtained the names of _Red Precipitate_, and _Arcanum
Corallinum_. This Precipitate, as well as Turbith, is less volatile
than pure Mercury.
If this solution of Mercury be mixed with a solution of Copper, made
likewise in the nitrous acid, and the mixture evaporated to dryness,
there will remain a green powder called _Green Precipitate_. These
precipitates are caustic and corrosive; and are used as such in surgery.
Though Mercury be dissolved more easily and completely by the nitrous
acid than by the vitriolic, yet it has a greater affinity with the
latter than with the former: for if a vitriolic acid be poured into
a solution of Mercury in spirit of nitre, the Mercury will quit the
latter acid in which it was dissolved, and join the other which was
added. The same thing happens when the marine acid is employed instead
of the vitriolic.
Mercury combined with spirit of salt forms a singular body; a metalline
salt which shoots into long crystals, pointed like daggers. This
salt is volatile, and sublimes easily without decomposition. It is
moreover the most violent of all the corrosives hitherto discovered
by Chymistry. It is called _Corrosive Sublimate_, because it must
absolutely be sublimed to make the combination perfect. There are
several ways of doing this: but the operation will never fail, if the
Mercury be rarefied into vapours, and meet with the marine acid in a
similar state.
Corrosive Sublimate is dissolved by water, but in very small quantities
only. It is decompounded by fixed alkalis, which precipitate the
Mercury in a reddish yellow powder, called, on account of its colour,
_Yellow Precipitate_.
If Corrosive Sublimate be mixed with tin, and the compound distilled,
a liquor comes over which continually emits abundance of dense fumes,
and, from the name of its inventor, is called the _Smoking Liquor
of Libavius_. This liquor is no other than the tin combined with
the marine acid of the Corrosive Sublimate, which therefore it hath
actually decompounded: whence it follows, that this acid hath a greater
affinity with tin than with Mercury.
Public-domain text, read in full here on John Shaqi.
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