Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
As in the operation for preparing _Regulus of Antimony per se_, some of
the nitre is, by the inflammable matters added thereto, turned to an
alkali, this alkali seizes on part of the Antimony, and therewith forms
a compound like that just described. Hence it comes, that if the scoria
formed in this process be dissolved in water, and an acid dropped into
the solution, a true golden sulphur of Antimony is thereby separated.
This union of Antimony with an alkali may also be brought about by the
humid way; that is, by making use of an alkali resolved into a liquor,
and boiling the mineral in it. The alkaline liquor, in proportion as
it acts upon the Antimony, gradually becomes reddish and turbid. If
left to settle and cool when well saturated therewith, it gradually
deposites the Antimony it had taken up, which precipitates in the form
of a red powder; and this precipitate is the celebrated remedy known
by the name of _Kermes Mineral_. It is plain that the kermes is nearly
the same thing with the golden sulphur: yet it differs from it in some
respects; and especially in this, that being taken inwardly it operates
much more gently than the golden sulphur, which is a violent emetic.
Nitre fixed by charcoal, and resolved into a liquor, is the only alkali
employed in preparing the kermes.
It was shewn above, that Regulus of Antimony mixed and distilled with
corrosive sublimate decompounds it, disengages the Mercury, and joining
itself to the marine acid forms therewith a new combination, called
Butter of Antimony. If the same operation be performed with crude
Antimony instead of its Regulus, the same effects are produced: but
then the Antimony itself is also decomposed; that is, the reguline
part is separated from the sulphur, which being set free unites with
the Mercury, now also at liberty, and these two together form a true
cinabar, called _Cinabar of Antimony_.
SECTION II.
_Of_ BISMUTH.
Bismuth, known also by the name of Tin-glass, is a semi-metal, having
almost the same appearance as Regulus of Antimony; yet it has a
more dusky cast, inclining somewhat to red, and even presents some
changeable streaks, especially after lying long in the air.
When exposed to the fire it melts long before it is red, and
consequently with less heat than Regulus of Antimony, which does not
flow, as was shewn above, till it begin to be red-hot. It becomes
volatile, like all the other semi-metals, when acted on by a violent
fire: being kept in fusion by a proper degree of heat it loses its
phlogiston with its metallic form, and turns to a powder or a calx; and
that again is converted into glass by the continued action of fire. The
calx and glass of Bismuth may be reduced, like any other metallic calx,
by restoring their phlogiston.
Bismuth mixes with all the metals in fusion, and even facilitates the
fusion of such as do not otherwise flow readily. It whitens them by its
union, and destroys their malleability.
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