Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Again, if three parts of nitre be taken to one of Antimony, the Regulus
is thereby entirely robbed of its phlogiston, and converted to a white
calx, which bears the name of _Diaphoretic Antimony_, or _Diaphoretic
Mineral_. The pearly matter may be precipitated by pouring an acid
on the saline substances which here remain after the detonation, in
the same manner as we shewed above was to be done with regard to the
Regulus.
In the two last operations, where the nitre is in a double or triple
proportion to the Antimony, the reguline part is found after the
detonation to be converted into a calx, and not into a half-vitrified
matter, which we have seen is the effect when equal parts only of nitre
and Antimony are used. The reason of this difference is, that in these
two cases the reguline part, being wholly, or almost wholly, deprived
of its phlogiston, becomes, as was observed, more difficult to fuse,
and consequently cannot begin to vitrify in the same degree of heat
as that which hath not lost so much of its phlogiston. If, instead of
performing the operation with equal parts of nitre and Antimony alone,
a portion of some substance which abounds with phlogiston be added, in
that case the sulphur only of the Antimony will be consumed, and the
Regulus will remain united with its phlogiston and separated from its
sulphur.
The Regulus prepared in this manner is absolutely pure, because no
metalline substance being employed, none can mix with and adulterate
it. It is called _Regulus of Antimony per se_, or only _Regulus of
Antimony_.
It is true indeed that in this operation much of the reguline part
unavoidably loses its phlogiston and is calcined, and consequently
a much smaller quantity of Regulus is obtained than when metalline
precipitants are employed: but this loss is easily repaired, if it be
thought proper, by restoring to the calcined part its lost phlogiston.
Antimony melted with two parts of fixed alkali yields no Regulus,
but is entirely dissolved by the salt, and forms with it a mass of a
reddish yellow colour.
The reason why no precipitate is produced on this occasion is, that the
alkali uniting with the sulphur of the Antimony forms therewith the
combination called Liver of Sulphur, which by its nature is qualified
to keep the reguline part dissolved. This mass formed by the union of
the Antimony with the alkali is soluble in water. If any acid whatever
be dropt into this solution, there falls a precipitate of a reddish
yellow colour; because the acid unites with the alkali, and forces it
to quit the matters with which it was combined. This precipitate is
called _Golden Sulphur of Antimony_.
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