Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Zinc melts the moment it grows red in the fire, and then also begins
to turn to a calx, which, like any other metallic calx, may be reduced
by means of the phlogiston: but if the fire be considerably increased,
it sublimes, flames, and burns like an oily matter; which is a proof
of the great quantity of phlogiston in its composition. At the same
time abundance of flowers rise from it in the form of white flakes,
flying about in the air like very light bodies; and into this form
may the whole substance of the Zinc be converted. Several names have
been given to these flowers, such as Pompholyx, Philosophic Wool.
They are supposed to be no other than the Zinc itself deprived of its
phlogiston; yet no body has hitherto been able to resuscitate them
in the form of Zinc, by restoring their phlogiston according to the
methods used in the reduction of metals. Though they rise in the air
with very great ease while the Zinc is calcining, yet when once formed
they are very fixed; for they withstand the utmost violence of fire,
and are capable of being vitrified, especially if joined with a fixed
alkali. They are soluble in acids.
Zinc unites with all metalline substances, except Bismuth. It has
this singular property, that being mixed with Copper, even in a
considerable quantity, such as a fourth part, it does not greatly
lessen the ductility thereof, and at the same time communicates to it
a very beautiful colour not unlike that of Gold: on which account the
composition is frequently made, and produces what is called _Brass_.
This metal melts much more easily than Copper alone, because of the
Zinc with which it is alloyed. If it be exposed to a great degree of
heat, the Zinc which it contains takes fire, and sublimes in white
flowers, just as when it is pure.
It is to be observed, that Brass is ductile only while it is cold, and
not then, unless the Zinc used in making it was very pure; otherwise
the composition will prove but a _Tombac_ or _Prince's Metal_, having
very little malleability.
Zinc is very volatile, and carries off with it any metallic substance
with which it is fused, making a kind of sublimate thereof. In the
furnaces where they smelt ores containing Zinc, the matter thus
sublimed is called _Cadmia Fornacum_, to distinguish it from the
native _Cadmia_ called also _Calamine_, or _Lapis Calaminaris_; which,
properly speaking, is an ore of Zinc, containing a great deal of that
semi-metal, together with some Iron, and a stony substance. The name of
_Cadmia Fornacum_ is not appropriated solely to the metallic sublimates
procured by means of Zinc, but is given in general to all the metallic
sublimates found in smelting houses.
If a violent and sudden heat be applied to Zinc, it sublimes in its
metalline form; there not being time for it to burn and be resolved
into flowers.
This semi-metal is soluble in all the acids, but especially in spirit
of nitre, which attacks and dissolves it with very great violence.
Public-domain text, read in full here on John Shaqi.
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