Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Zinc has a greater affinity than iron or copper with the vitriolic
acid; and therefore it decompounds the green and blue vitriols,
precipitating those two metals by uniting with the vitriolic acid, with
which it forms a metallic salt, or vitriol, called _White Vitriol_, or
_Vitriol of Zinc_.
Nitre mixed with Zinc, and projected into a red-hot crucible, detonates
with violence, and during the detonation there rises a great quantity
of white flowers, like those which appear when it is calcined by itself.
Sulphur has no power over Zinc. Even liver of sulphur, which dissolves
all other metallic substances, contracts no union with this semi-metal.
Messrs. Hellot and Malouin have bestowed a great deal of pains on this
semi-metal. An account of their experiments is to be found in the
Memoirs of the Academy of Sciences.
SECTION IV.
_Of_ REGULUS OF ARSENIC.
Regulus of Arsenic is the most volatile of all the semi-metals. A very
moderate heat makes it wholly evaporate, and fly off in fumes; on which
account it cannot be brought to fusion, nor can any considerable masses
thereof be obtained. It has a metallic colour, somewhat resembling
Lead; but it soon loses its splendour when exposed to the air.
It unites readily enough with metallic substances, having the same
affinities with them as Regulus of Antimony hath. It makes them
brittle, and unmalleable. It hath also the property of rendering them
volatile, and greatly facilitates their scorification.
It very easily parts with its phlogiston and its metallic form. When
exposed to the fire it rises in a kind of shining crystalline calx,
which, on that account, looks more like a saline matter than a metallic
calx. To this calx or these flowers are given the names of _White
Arsenic_, _Crystalline Arsenic_, and most commonly plain _Arsenic_.
The properties of this substance are very singular, and extremely
different from those of any other metallic calx. Hitherto it hath been
but little examined; and this led me to make some attempts towards
discovering its nature, which may be seen in the Memoirs of the Academy
of Sciences.
Arsenic differs from every other metalline calx, first, in being
volatile; whereas the calces of all other metallic substances, not
excepting those of the most volatile semi-metals, such as Regulus of
Antimony and Zinc, are exceeding fixed; and, secondly, in having a
saline character, which is not found in any other metalline calx.
Public-domain text, read in full here on John Shaqi.
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