Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Charcoal is unalterable and indestructible by any other body but fire;
whence it follows, that when it is not actually kindled and ignited,
the most powerful agents, such as the acids, though ever so strong and
concentrated, have not the least effect on it.
The case is otherwise when it is lighted, that is, when its phlogiston
begins to separate from its earth; for then the pure acid of vitriol
being joined therewith, contracts an instantaneous union with its
phlogiston, and evaporates in a volatile sulphureous spirit. If the
vitriolic acid, instead of being applied quite pure, be first clogged
with some basis, especially an alkaline one, it quits that basis,
enters into a more intimate union with the phlogiston of the burning
Coal, and so forms an actual sulphur, with which the alkali now unites
and forms a hepar.
The pure acid of sea-salt hath not been observed to act in the least
upon Charcoal, especially when it is not on fire. But when this acid
is incorporated with an alkaline or metallic basis, and combined
according to a peculiar process with burning Charcoal, it in like
manner quits its basis, unites with the phlogiston, and therewith forms
a phosphorus, of which we have already taken notice.
Nor has the pure nitrous acid any effect on a charred Coal, even when
ignited: and so far is it from being able to kindle a cold one, that
when poured on a live one, it extinguishes it like water. But when
this acid is united with a basis, it quits it rapidly as soon as it
touches a burning coal, and rushes violently into an union with the
phlogiston thereof. From this union there probably arises, as we said
before, a kind of sulphur or phosphorus, which is so inflammable as to
be destroyed by the fire the very moment it is generated.
The acids of nitre and vitriol act upon Oils; but very differently,
according to the quantity of phlegm they contain. If they be weakened
with much water, they have no effect at all upon Oils; if they contain
little water, or be dephlegmated to a certain degree, they dissolve
them with heat, and with them form compounds of a thick consistence.
Acids, thus combined in a considerable proportion with Oils, render
them soluble in water.
SECTION II.
_Of_ SOAP.
Alkalis also have the same property. When an Oil is combined with an
acid or an alkali in such a manner, that the compound resulting from
their union is soluble in water; such a compound may in general be
called a _Soap_. Soap itself hath the property of rendering fat bodies
in some measure soluble in water; on which account it is very useful
for scouring or cleansing any thing greasy.
Public-domain text, read in full here on John Shaqi.
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