Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The inflammability of Oil evidently proves that it contains the
phlogiston. That an acid is one of its constituent principles many
experiments demonstrate, of which these are the chief: If certain Oils
be long triturated with an alkaline salt, and the alkali afterwards
dissolved in water, crystals of a true neutral salt will be produced:
some metals, and particularly Copper, are corroded and rusted by Oils,
just as they are by acids: again, acid crystals are found in some Oils
that have been long kept. This acid in Oil serves undoubtedly to unite
its phlogiston with its water; because these two substances having no
affinity with each other cannot be united without the intervention of
such a medium as an acid, which has an affinity with both. As to the
existence of water in Oils, it appears plainly when they are decomposed
by repeated distillations, especially after mixing them with absorbent
earths. Lastly, when an Oil is destroyed by burning, a certain quantity
of earth is constantly left behind.
We are very sure that the above-mentioned principles enter into the
composition of Oils; for they may be obtained from every one of them:
but it is not absolutely certain that they consist of these only, and
that they do not contain some other principle which may escape our
notice in decomposing them; for hitherto it doth not appear, by any
experiment we can depend on, that Oil was ever produced by combining
together the principles here specified: yet such redintegrations are
the only means we have of satisfying ourselves that we know all the
principles which constitute a body.
Oils exposed to the fire in close vessels pass over almost wholly from
the containing vessel into any other applied to receive them. There
remains, however, a small quantity of black matter, which is extremely
fixed, and continues unalterable as long as it hath no communication
with the external air, be the force of the fire ever so violent. This
matter is no other than part of the phlogiston of the Oil united
with its most fixed and grossest earth; and this is what we called
_Charcoal_, or plainly a _Coal_.
SECTION I.
_Of_ CHARCOAL.
When Oil happens to be united to much earth, as it is in vegetable and
animal bodies, it leaves a considerable quantity of _Coal_ or charred
matter.
This Coal, exposed to the fire in the open air, burns and wastes,
but without blazing like other combustible matters: there appears
only a small blueish flame, but not the least smoke. Most commonly
it only glows and sparkles, and so gradually falls into ashes, which
are nothing but the earth of the body, combined with an alkaline salt
in burning. This alkaline salt may be separated from the earth, by
lixiviating the ashes with water, which dissolves all the salt, and
leaves the earth quite pure.
Public-domain text, read in full here on John Shaqi.
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