Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
These Oils, being exposed to the air for some time, sooner or latter
grow thick, acquire an acrid taste, and a strong disagreeable smell.
Some of them congeal with the smallest degree of cold. This sort of
Oil is well adapted to dissolve those preparations of Lead called
Litharge and Minium, with which they form a thick tenacious substance,
that is used for the basis of almost all plasters. They also dissolve
Lead in its metalline form; but not so easily as the sorts of calx
above-mentioned; probably because its body is not so much opened, nor
its parts so divided.
By expression alone we also procure from certain vegetable substances
another sort of Oil, which is thin, limpid, volatile, of a pungent
taste, and retains the smell of the vegetable that yielded it; on which
account it is called an _Essential Oil_. Of this there are several
sorts, differing from one another, like the Fat Oils, according to the
subjects from which they are obtained.
We must observe, that it is very difficult, or rather in most
cases impossible, to force from the greatest part of vegetables,
by expression only, all the essential Oil they contain. For this
purpose therefore recourse must be had to fire: a gentle heat, not
exceeding that of boiling water, will extract all the essential Oils
of vegetables; and this is the most usual and most convenient way of
procuring them.
The fat Oils cannot be obtained by the same method: these being much
less volatile than the essential Oils, require a much greater degree of
heat to raise them; which nevertheless they cannot bear without being
much spoiled and entirely changed in their nature, as shall presently
be shewn. All Oils, therefore, which rise with the heat of boiling
water, and such alone, should be called Essential Oils.
Essential Oils, in a longer or shorter time, according to the nature
of each, lose the fragrant smell they had when newly distilled, and
acquire another, which is strong, rancid, and much less agreeable: they
also lose their tenuity, becoming thick and viscid; and in this state
they greatly resemble those substances abounding in Oil which flow from
certain trees, and which are called _Balsams_ or _Resins_, according as
they are less or more consistent.
Balsams and Resins are not soluble in water. But there are other Oily
compounds which likewise run from trees; and, though not unlike Resins,
are however soluble in water. These are called _Gums_; and their
property of dissolving in water arises from their containing more water
and more salt than Resins have; or at least their saline parts are less
clogged and more disengaged.
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