Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Balsams and Resins distilled with the heat of boiling water yield
great quantities of a limpid, subtile, odoriferous, and, in one word,
essential Oil. In the still there remains a substance thicker and more
consistent than the Balsam or Resin was before distillation. The same
thing happens to essential Oils which by length of time have acquired
a consistence and are grown resinous. If they be re-distilled, they
recover their former tenuity, leaving behind them a remainder thicker
and more resinous than they themselves were. This second distillation
is called the _Rectification_ of an Oil.
It must be observed, that an essential Oil, combined with an acid
strong enough to dissolve it, immediately becomes as thick and
resinous, in consequence of this union, as if it had been long exposed
to the air: which proves the consistence an Oil acquires by long
keeping to be owing to this, that its lightest and less acid parts
being evaporated, the proportion of its acid to the remainder is so
increased, that it produces therein the same change, as an additional
acid mixed with the Oil would have wrought before the evaporation.
This also shews us, that Balsams and Resins are only essential Oils
combined with a great proportion of acid, and thereby thickened.
If vegetable substances, from which no more essential Oil can be drawn
by the heat of boiling water, be exposed to a stronger heat, they yield
an additional quantity of Oil; but it is thicker and heavier than the
essential Oil. These Oils are black, and have a very disagreeable burnt
smell, which hath made them be called _Fetid_ or _Empyreumatic_ Oils.
They are moreover very acrid.
It must be observed, that, if a vegetable substance be exposed to a
degree of heat greater than that of boiling water, before the fat or
the essential Oil is extracted from it, an empyreumatic Oil only will
then be obtained; because both the fat and essential Oils, when exposed
to the force of fire, are thereby burnt, rendered acrid, acquire a
smell of the fire, and, in a word, become truly empyreumatic. There
is ground to think, that an empyreumatic Oil is nothing else but an
essential or fat Oil burnt and spoiled by the fire, and that no other
Oil besides these two exists naturally in vegetables.
Empyreumatic Oils, distilled and rectified several times by a gentle
heat, acquire by every distillation a greater degree of tenuity,
lightness, and limpidity. By this means also they lose something of
their disagreeable odour; so that they gradually come nearer and
nearer to the nature of essential Oils: and if the rectifications be
often enough repeated, ten or twelve times for instance, they become
perfectly like those Oils; except that their smell will never be
so agreeable, nor like that of the substances from which they were
obtained.
Fat Oils may also be brought by the same means to resemble essential
Oils: but neither essential nor empyreumatic Oils are capable of
acquiring the properties of fat Oils.
SECTION III.
Public-domain text, read in full here on John Shaqi.
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