Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
By distillation we draw from Wine an inflammable liquor, of a yellowish
white colour, light, and of a penetrating, pleasant smell. This
liquor is the truly spirituous part of the wine, and the product
of fermentation. That which comes off in the first distillation is
commonly loaded with much phlegm and some oily parts, from which it may
be afterwards freed. In this state it goes by the name of _Brandy_; but
when freed from these heterogeneous matters by repeated distillations,
it becomes still clearer, lighter, more fragrant, and much more
inflammable, and then is called _Spirit of Wine_, and _Rectified
Spirit of Wine_, or an _Ardent Spirit_, if considerably purified. The
properties which distinguish an Ardent Spirit from all other substances
are its being inflammable; its burning and consuming entirely, without
the least appearance of smoke or fuliginosity; its containing no
particles reducible to a coal; and its being perfectly miscible with
water. Ardent Spirits are lighter and more volatile than any of the
principles of the mixts from which they were produced, and consequently
more so than the phlegm, the acid, and the oil of which they themselves
consist. This arises from a particular disposition of these principles,
which are in a singular manner attenuated by fermentation, and thereby
rendered more susceptible of expansion and rarefaction.
Ardent spirits are supposed to be the natural solvents of oils and oily
matters. But it is very remarkable that they dissolve essential oils
only, without touching the fat of animals, or the fat oils obtained
from vegetables by expression; yet when these oils have once undergone
the action of fire, they become soluble in spirit of wine, and even
acquire a new degree of solubility every time they are distilled. It is
not so with essential oils, which can never be rendered more soluble in
ardent spirits than they are at first; and are so far from acquiring
a new degree of solubility every time they are distilled, that on the
contrary they even in some measure lose that property by repeated
rectifications.
I have taken some pains to find out the causes of these singular
effects, and the result of my inquiries is published among the Memoirs
of the Academy of Sciences for the year 1745. I therein consider ardent
spirits as consisting of an oil, or at least a phlogiston, mixed with a
portion of water, in which it is rendered soluble by means of an acid.
This being laid down, I shew that the inability of spirit of wine to
dissolve some oils must be imputed to its aqueous part, in which oils
are not naturally soluble without the intervention of a salt: and that
the power which this spirit exerts in dissolving other oils with ease,
such as essential oils, must in all probability be owing to this, that
in these oils it meets with the necessary saline medium, that is, with
an acid, which numberless experiments shew they actually contain.
Public-domain text, read in full here on John Shaqi.
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