Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
On the other hand, I there prove, that the acid in essential oils is
super-abundant, and in some sort foreign to their nature, or that it
is but slightly connected with them, and in part deserts them every
time they are distilled; which renders them less soluble after every
new rectification: whereas, on the contrary, the fat expressed oils in
their natural state give not the least sign of acidity, but the action
of fire upon them discovers an acid which was not perceivable before.
Hence I conjecture, that these oils contain no more acid than is just
necessary to constitute them oils; that this acid is intimately blended
with their other component parts; that it is so sheathed and entangled
by these parts as to be incapable of exerting any of its properties;
and that on this account these oils in their natural state are not
soluble in spirit of wine: but that the disposition of their parts
being gradually changed by the fire, and their acid, being by that
means set more and more at liberty, at length recovers its properties,
and particularly that of rendering the oily parts soluble in an aqueous
menstruum: and hence it follows, that the fat oils become so much the
more soluble in spirit of wine the oftener they are exposed to the
action of fire.
Spirit of wine doth not dissolve fixed alkalis; or at least it takes
up but a very small quantity thereof; and hence ardent spirits may be
freed from much of their phlegm by means of these salts thoroughly
dried: for as they strongly imbibe moisture, and have even a greater
affinity than ardent spirits with water, if a fixed alkali, well
exsiccated, be mixed with spirit of wine that is not perfectly
dephlegmated, the alkali immediately attracts its superfluous moisture,
and is thereby resolved into a liquor, which, on account of its
gravity, descends to the bottom of the vessel. The spirit of wine,
which swims at top, is by this means as much dephlegmated, and as dry,
as if it had been rectified by several distillations. As it takes up
some alkaline particles in this operation, it is thereby qualified to
dissolve oily matters with the greater facility. When rectified in
this manner, it is called _Alcoholized Spirit of Wine_.
Yet spirit of wine, even when rectified to an alcohol, is not capable
of dissolving all oily matters. Those named Gums will by no means
enter into any sort of union therewith; but it readily dissolves most
of those which are known by the appellation of Resins. When it has
dissolved a certain proportion of resinous particles it acquires a
greater consistence, and forms what is called a _Spirit Varnish_, or a
_Drying Varnish_, because it soon dries. This Varnish is subject to be
damaged by water. Many sorts thereof are prepared, differing from each
other according to the different resins employed, or the proportions
in which they are used. Most of these Varnishes are transparent and
colourless.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account