Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The acid of Vinegar is always clogged with a certain proportion of
oily parts, which greatly weaken it, and deprive it of much of its
activity; and for this reason it is not near so strong as the mineral
acids, which are not entangled with any oil. By distillation, indeed,
it may be freed from this oil, and at the same time from the great
quantity of water which in a manner suffocates it, and by that means
may be brought much nearer to the nature of the mineral acids: but this
attempt hath not yet been prosecuted with the assiduity it deserves.
Besides distillation, there is another way of freeing Vinegar from a
good deal of its phlegm; and that is, by exposing it to a hard frost,
which readily congeals the watery part into ice, while the acid retains
its fluidity.
Vinegar, saturated with a fixed alkali, forms a neutral oily salt, of
a dark colour, which is semi-volatile, melts with a very gentle heat,
flames when thrown upon burning coals, and dissolves in spirit of wine,
of which, however, it requires six parts to complete the solution.
This solution being evaporated to dryness leaves a matter in the form
of leaves lying on each other; on which account it hath obtained the
name of _Terra Foliata_. The same foliated matter will be obtained,
though the salt be not previously dissolved in spirit of wine; but not
so readily. This salt is also called _Regenerated Tartar_. Under the
head of Tartar we shall see the reason of these different appellations.
Regenerated Tartar is also in some degree capable of crystallizing: for
this purpose a solution thereof in water must be slowly evaporated to
the consistence of a syrup, and then suffered to stand quiet in a cool
place; by which means it will shoot into clusters of crystals, lying
one upon another, not unlike the feathers on a quill.
With Vinegar and several absorbent earths, such as calcined pearls,
coral, shells of fish, _&c._ are also formed neutral saline compounds,
each of which takes the name of the particular earth employed in its
composition.
Vinegar perfectly dissolves Lead, and converts it to a neutral metallic
salt, which shoots into crystals, and has a sweet saccharine taste.
This compound is called _Sugar of Lead_, or _Sal Saturni_.
If Lead be exposed to the bare vapour of Vinegar, it will be thereby
corroded, calcined, and converted into a white matter much used in
painting, and known by the name of _Ceruse_; or, when it is finer than
ordinary, _White Lead_.
Vinegar corrodes Copper likewise, and converts it into a beautiful
green rust, which also is used in painting; and distinguished by the
name of _Verdegris_. However, Vinegar is not commonly employed to make
Verdegris: for this purpose they use wine, or the rape of wine, from
which fire extricates an acid analogous to that of Vinegar.
Public-domain text, read in full here on John Shaqi.
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