Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
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Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Besides an ardent spirit, wine affords a great deal of water, oil,
earth, and a sort of acid which shall be considered presently. When
the spirituous part is separated from these other matters, they
undergo no further change. But if all the constituent parts of wine
remain combined together, then, after some time, shorter or longer as
the degree of heat in which the wine stands is greater or less, the
fermentation begins afresh, or rather arrives at its second stage. The
liquor once more grows turbid, a new intestine motion arises, and,
after some days, it is found changed into an acid; which, however,
is very different from those hitherto treated of. The liquor then
takes the name of _Vinegar_. The acetous fermentation differs from
the spirituous, not only in its effect, but also in several of its
concomitant circumstances. Moderate motion is of service to this,
whereas it obstructs the spirituous; and it is attended with much more
warmth than the spirituous. The vapours it produces are not noxious,
like those of fermenting wine. Lastly, Vinegar deposites no tartar,
even when the wine employed in this operation is quite new, and hath
not had time to discharge its tartar: instead of tartar, Vinegar
deposites a viscid matter which is very apt to putrify.
It must be observed, that wine is not the only substance that is
susceptible of the acetous fermentation: for several vegetable and even
animal matters, which are not subject to the spirituous fermentation,
turn sour before they putrify. But as vinous liquors possess in a
very eminent degree the property of being susceptible of the acetous
fermentation, and likewise of producing the strongest acids that can
result from such fermentation, their acid shall be more particularly
considered in this place.
SECTION I.
_Of_ VINEGAR.
If wine, which has gone through this second stage of fermentation,
be distilled, instead of an ardent spirit, only an acid liquor is
obtained, which is called _Distilled Vinegar_.
This acid has the same properties as the mineral acids of which we have
already treated; that is, it unites with alkaline salts, absorbent
earths, and metallic substances, and therewith forms neutral saline
combinations.
Its affinity with these substances observes the same order as that
observed by the mineral acids with regard to the same substances;
but in general it is weaker; that is, any mineral acid is capable of
expelling the acid of Vinegar out of all matters with which it is
united.
Vinegar hath likewise a greater affinity than sulphur with alkalis:
whence it follows, that it is capable of decompounding that combination
of sulphur with an alkali called Liver of Sulphur, and of precipitating
the sulphur it contains.
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