a pointed electrode equal to a small multiple of the radius of curvature
of its extremity the electric intensity falls very far below that
required to produce discharge in a uniform field, so that the discharge
from a pointed electrode ought to be compared with a spark whose length
is comparable with the radius of curvature of the point. For such short
sparks the electric intensity is very high. The electric intensity
required to produce the discharge from a gas diminishes as the pressure
of the gas diminishes, but not nearly so rapidly as the electric
intensity for long sparks. Here again the discharge from a point is
comparable with short sparks, which, as we have seen, are much less
sensitive to pressure changes than longer ones. The minimum potential at
which the electricity streams from the point does not depend upon the
material of which the point is made; it varies, however, considerably
with the nature of the gas. The following are the results of some
experiments on this point. Those in the first two columns are due to
Röntgen, those in the third and fourth to Precht:--
+------+-----------------------------+--------------------+
| |Discharge Potential. Point +.| Pressure 760. |
| Gas. +--------------+--------------+----------+---------+
| | Pressure 205.| Pressure 110.| Point +. | Point -.|
+------+--------------+--------------+----------+---------+
| | Volts. | Volts. | Volts. | Volts. |
| H2 | 1296 | 1174 | 2125 | 1550 |
| O2 | 2402 | 1975 | 2800 | 2350 |
| CO | 2634 | 2100 | .. | .. |
| CH4 | 2777 | 2317 | .. | .. |
| NO | 3188 | 2543 | .. | .. |
| CO2 | 3287 | 2655 | 3475 | 2100 |
| N2 | .. | .. | 2600 | 2000 |
| Air | .. | .. | 2750 | 2050 |
+------+--------------+--------------+----------+---------+
We see from this table that in the case of the discharge from a
positively electrified point the greater the molecular weight of the gas
the greater the potential required for discharge. Röntgen concluded from
his experiments that the discharging potential from a positive point in
different gases at the same pressure varies inversely as the mean free
path of the molecules of the gas. In the same gas, however, at different
pressures the discharging potential does not vary so quickly with the
pressure as does the mean free path. In Precht's experiments, in which
different gases were used, the variations in the discharging potential
are not so great as the variations in the mean free path of the gases.
Public-domain text, read in full here on John Shaqi.
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