With a given potential difference between the point and the neighbouring
conductor the current issuing from the point is greater when the point
is negative than when it is positive, except in oxygen, when it is less.
Warburg (_Sitz. Akad. d. Wissensch. zu Berlin_, 1899, 50, p. 770) has
shown that the addition of a small quantity of oxygen to nitrogen
produces a great diminution in the current from a negative point, but
has very little effect on the discharge from a positive point. Thus the
removal of a trace of oxygen made a leak from a negative point 50 times
what it was before. Experiments with hydrogen and helium showed that
impurities in these gases had a great effect on the current when the
point was negative, and but little when it was positive. This suggests
that the impurities, by condensing round the negative ions as nuclei,
seriously diminish their velocity. If a point is charged up to a high
and rapidly alternating potential, such as can be produced by the
electric oscillations started when a Leyden jar is discharged, then in
hydrogen, nitrogen, ammonia and carbonic acid gas a conductor placed in
the neighbourhood of the point gets a negative charge, while in air and
oxygen it gets a positive one. There are two considerations which are of
importance in connexion with this effect. The first is the velocity of
the ions in the electric field, and the second the ease with which the
ions can give up their charges to the metal point. The greater velocity
of the negative ions would, if the potential were rapidly alternating,
cause an excess of negative ions to be left in the surrounding gas. This
is the case in hydrogen. If, however, the metal had a much greater
tendency to unite with negative than with positive ions, such as we
should expect to be the case in oxygen, this would act in the opposite
direction, and tend to leave an excess of positive ions in the gas.
Public-domain text, read in full here on John Shaqi.
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