Effects of Heat.--Temperature affects the resistivity of these different
classes of conductors in different ways. In all cases, so far as is yet
known, the resistivity of a pure metal is increased if its temperature is
raised, and decreased if the temperature is lowered, so that if it could
be brought to the absolute zero of temperature (-273° C.) its resistivity
would be reduced to a very small fraction of its resistance at ordinary
temperatures. With metallic alloys, however, rise of temperature does not
always increase resistivity: it sometimes diminishes it, so that many
alloys are known which have a maximum resistivity corresponding to a
certain temperature, and at or near this point they vary very little in
resistance with temperature. Such alloys have, therefore, a negative
temperature-variation of resistance at and above fixed temperatures.
Prominent amongst these metallic compounds are alloys of iron, manganese,
nickel and copper, some of which were discovered by Edward Weston, in the
United States. One well-known alloy of copper, manganese and nickel, now
called manganin, which was brought to the notice of electricians by the
careful investigations made at the Berlin Physikalisch-Technische
Reichsanstalt, is characterized by having a zero temperature coefficient
at or about a certain temperature in the neighbourhood of 15° C. Hence
within a certain range of temperature on either side of this critical
value the resistivity of manganin is hardly affected at all by
temperature. Similar alloys can be produced from copper and
ferro-manganese. An alloy formed of 80% copper and 20% manganese in an
annealed condition has a nearly zero temperature-variation of resistance
between 20° C. and 100° C. In the case of non-metals the action of
temperature is generally to diminish the resistivity as temperature
rises, though this is not universally so. The interesting observation has
been recorded by J. W. Howell, that "treated" carbon filaments and
graphite are substances which have a minimum resistance corresponding to
a certain temperature approaching red heat (_Electrician_, vol. xxxviii.
p. 835). At and beyond this temperature increased heating appears to
increase their resistivity; this phenomenon may, however, be accompanied
by a molecular change and not be a true temperature variation. In the
case of dielectric conductors and of electrolytes, the action of rising
temperature is to reduce resistivity. Many of the so-called insulators,
such as mica, ebonite, indiarubber, and the insulating oils, paraffin,
&c., decrease in resistivity with great rapidity as the temperature
rises. With guttapercha a rise in temperature from 0° C. to 24° C. is
sufficient to reduce the resistivity of one-twentieth part of its value
at 0° C., and the resistivity of flint glass at 140° C. is only
one-hundredth of what it is at 60° C.
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