The form of vessel chosen to contain the electrolyte depends on the
order of resistance to be measured. For dilute solutions the shape of
cell shown in fig. 2 will be found convenient, while for more
concentrated solutions, that indicated in fig. 3 is suitable. The
absolute resistances of certain solutions have been determined by
Kohlrausch by comparison with mercury, and, by using one of these
solutions in any cell, the constant of that cell may be found once for
all. From the observed resistance of any given solution in the cell the
resistance of a centimetre cube--the so-called specific resistance--may
be calculated. The reciprocal of this, or the conductivity, is a more
generally useful constant; it is conveniently expressed in terms of a
unit equal to the reciprocal of an ohm. Thus Kohlrausch found that a
solution of potassium chloride, containing one-tenth of a gram
equivalent (7.46 grams) per litre, has at 18° C. a specific resistance
of 89.37 ohms per centimetre cube, or a conductivity of 1.119 × 10^-2
mhos or 1.119 × 10^-11 C.G.S. units. As the temperature variation of
conductivity is large, usually about 2% per degree, it is necessary to
place the resistance cell in a paraffin or water bath, and to observe
its temperature with some accuracy.
Another way of eliminating the effects of polarization and of dilution
has been used by W. Stroud and J. B. Henderson (_Phil. Mag._, 1897 [5],
43, p. 19). Two of the arms of a Wheatstone's bridge are composed of
narrow tubes filled with the solution, the tubes being of equal diameter
but of different length. The other two arms are made of coils of wire of
equal resistance, and metallic resistance is added to the shorter tube
till the bridge is balanced. Direct currents of somewhat high
electromotive force are used to work the bridge. Equal currents then
flow through the two tubes; the effects of polarization and dilution
must be the same in each, and the resistance added to the shorter tube
must be equal to the resistance of a column of liquid the length of
which is equal to the difference in length of the two tubes.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account