From this point of view W. K.
Bousfield has calculated the sizes of ions on the assumption that
Stokes's theory of the motion of a small sphere through a viscous medium
might be applied (_Zeits. phys. Chem._, 1905, 53, p. 257; _Phil. Trans._
A, 1906, 206, p. 101). The radius of the potassium or chlorine ion with
its envelope of water appears to be about 1.2 × 10^-8 centimetres.
For the bibliography of electrolytic conduction see ELECTROLYSIS. The
books which deal more especially with the particular subject of the
present article are _Das Leitvermögen der Elektrolyte_, by F.
Kohlrausch and L. Holborn (Leipzig, 1898), and _The Theory of Solution
and Electrolysis_, by W. C. D. Whetham (Cambridge, 1902).
(W. C. D. W.)
III. ELECTRIC CONDUCTION THROUGH GASES
A gas such as air when it is under normal conditions conducts
electricity to a small but only to a very small extent, however small
the electric force acting on the gas may be. The electrical conductivity
of gases not exposed to special conditions is so small that it was only
definitely established in the early years of the 20th century, although
it had engaged the attention of physicists for more than a hundred
years. It had been known for a long time that a body charged with
electricity slowly lost its charge even when insulated with the greatest
care, and though long ago some physicists believed that part of the leak
of electricity took place through the air, the general view seems to
have been that it was due to almost unavoidable defects in the
insulation or to dust in the air, which after striking the charged body
was repelled from it and went off with some of the charge. C. A.
Coulomb, who made some very careful experiments which were published in
1785 (_Mém. de l'Acad. des Sciences_, 1785, p. 612), came to the
conclusion that after allowing for the leakage along the threads which
supported the charged body there was a balance over, which he attributed
to leakage through the air. His view was that when the molecules of air
come into contact with a charged body some of the electricity goes on to
the molecules, which are then repelled from the body carrying their
charge with them. We shall see later that this explanation is not
tenable. C. Matteucci (_Ann. chim. phys._, 1850, 28, p. 390) in 1850
also came to the conclusion that the electricity from a charged body
passes through the air; he was the first to prove that the rate at
which electricity escapes is less when the pressure of the gas is low
than when it is high. He found that the rate was the same whether the
charged body was surrounded by air, carbonic acid or hydrogen.
Subsequent investigations have shown that the rate in hydrogen is in
general much less than in air. Thus in 1872 E. G. Warburg (_Pogg. Ann._,
1872, 145, p. 578) found that the leak through hydrogen was only about
one-half of that through air: he confirmed Matteucci's observations on
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