_Methods of counting the Number of Ions._--The detection of the ions and
the estimation of their number in a given volume is much facilitated by
the property they possess of promoting the condensation of water-drops
in dust-free air supersaturated with water vapour. If such air contains
no ions, then it requires about an eightfold supersaturation before any
water-drops are formed; if, however, ions are present C. T. R. Wilson
(_Phil. Trans._ 189, p. 265) has shown that a sixfold supersaturation is
sufficient to cause the water vapour to condense round the ions and to
fall down as raindrops. The absence of the drops when no ions are
present is due to the curvature of the drop combined with the surface
tension causing, as Lord Kelvin showed, the evaporation from a small
drop to be exceeding rapid, so that even if a drop of water were formed
the evaporation would be so great in its early stages that it would
rapidly evaporate and disappear. It has been shown, however (J. J.
Thomson, _Application of Dynamics to Physics and Chemistry_, p. 164;
_Conduction of Electricity through Gases_, 2nd ed. p. 179), that if a
drop of water is charged with electricity the effect of the charge is to
diminish the evaporation; if the drop is below a certain size the effect
the charge has in promoting condensation more than counterbalances the
effect of the surface tension in promoting evaporation. Thus the
electric charge protects the drop in the most critical period of its
growth. The effect is easily shown experimentally by taking a bulb
connected with a piston arranged so as to move with great rapidity. When
the piston moves so as to increase the volume of the air contained in
the bulb the air is cooled by expansion, and if it was saturated with
water vapour before it is supersaturated after the expansion. By
altering the throw of the piston the amount of supersaturation can be
adjusted within very wide limits. Let it be adjusted so that the
expansion produces about a sixfold supersaturation; then if the gas is
not exposed to any ionizing agents very few drops (and these probably
due to the small amount of ionization which we have seen is always
present in gases) are formed. If, however, the bulb is exposed to strong
Röntgen rays expansion produces a dense cloud which gradually falls down
and disappears. If the gas in the bulb at the time of its exposure to
the Röntgen rays is subject to a strong electric field hardly any cloud
is formed when the gas is suddenly expanded. The electric field removes
the charged ions from the gas as soon as they are formed so that the
number of ions present is greatly reduced. This experiment furnishes a
very direct proof that the drops of water which form the cloud are only
formed round the ions.
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