This method gives us an exceedingly delicate test for the presence of
ions, for there is no difficulty in detecting ten or so raindrops per
cubic centimetre; we are thus able to detect the presence of this number
of ions. This result illustrates the enormous difference between the
delicacy of the methods of detecting ions and those for detecting
uncharged molecules; we have seen that we can easily detect ten ions per
cubic centimetre, but there is no known method, spectroscopic or
chemical, which would enable us to detect a billion (10^12) times this
number of uncharged molecules. The formation of the water-drops round
the charged ions gives us a means of counting the number of ions present
in a cubic centimetre of gas; we cool the gas by sudden expansion until
the supersaturation produced by the cooling is sufficient to cause a
cloud to be formed round the ions, and the problem of finding the number
of ions per cubic centimetre of gas is thus reduced to that of finding
the number of drops per cubic centimetre in the cloud. Unless the drops
are very few and far between we cannot do this by direct counting; we
can, however, arrive at the result in the following way. From the amount
of expansion of the gas we can calculate the lowering produced in its
temperature and hence the total quantity of water precipitated. The
water is precipitated as drops, and if all the drops are the same size
the number per cubic centimetre will be equal to the volume of water
deposited per cubic centimetre, divided by the volume of one of the
drops. Hence we can calculate the number of drops if we know their size,
and this can be determined by measuring the velocity with which they
fall under gravity through the air.
The theory of the fall of a heavy drop of water through a viscous
fluid shows that v = (2/9)ga²/[mu], where a is the radius of the drop,
g the acceleration due to gravity, and [mu] the coefficient of
viscosity of the gas through which the drop falls. Hence if we know v
we can deduce the value of a and hence the volume of each drop and the
number of drops.
Public-domain text, read in full here on John Shaqi.
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