The mean of the values of Ne in the preceding table is 1.24 × 10^10.
Hence we may conclude that the charge of electricity carried by a
gaseous ion is equal to the charge carried by the hydrogen atom in the
electrolysis of solutions. The values of Ne for the different gases
differ more than we should have expected from the probable accuracy of
the determination of D and the velocity of the ions: Townsend (_Proc.
Roy. Soc._ 80, p. 207) has shown that when the ionization is produced
by Röntgen rays some of the positive ions carry a double charge and
that this accounts for the values of Ne being greater for the positive
than for the negative ions. Since we know the value of e, viz. 3.5 ×
10^-10, and, also Ne, = 1.24 × 10^10, we find N the number of
molecules in a cubic centimetre of gas at standard temperature and
pressure to be equal to 3.5 × 10^19. This method of obtaining N is the
only one which does not involve any assumption as to the shape of the
molecules and the forces acting between them.
Another method of determining the charge carried by an ion has been
employed by Rutherford (_Proc. Roy. Soc._ 81, pp. 141, 162), in which
the positively electrified particles emitted by radium are made use
of. The method consists of: (1) Counting the number of [alpha]
particles emitted by a given quantity of radium in a known time. (2)
Measuring the electric charge emitted by this quantity in the same
time. To count the number of the [alpha] particles the radium was so
arranged that it shot into an ionization chamber a small number of
[alpha] particles per minute; the interval between the emission of
individual particles was several seconds. When an [alpha] particle
passed into the vessel it ionized the gas inside and so greatly
increased its conductivity; thus, if the gas were kept exposed to an
electric field, the current through the gas would suddenly increase
when an [alpha] particle passed into the vessel. Although each [alpha]
particle produces about thirty thousand ions, this is hardly large
enough to produce the conductivity appreciable without the use of very
delicate apparatus; to increase the conductivity Rutherford took
advantage of the fact that ions, especially negative ones, when
exposed to a strong electric field, produce other ions by collision
against the molecules of the gas through which they are moving. By
suitably choosing the electric field and the pressure in the
ionization chamber, the 30,000 ions produced by each [alpha] particle
can be multiplied to such an extent that an appreciable current passes
through the ionization chamber on the arrival of each [alpha]
particle. An electrometer placed in series with this vessel will show
by its deflection when an [alpha] particle enters the chamber, and by
counting the number of deflections per minute we can determine the
number of [alpha] particles given out by the radium in that time.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account