Townsend has used the following method to compare the charge carried
by a gaseous ion with that carried by an atom of hydrogen in the
electrolysis of solution. We have
u/D = Ne/[Pi],
where D is the coefficient of diffusion of the ions through the gas, u
the velocity of the ion in the same gas when acted on by unit electric
force, N the number of molecules in a cubic centimetre of the gas when
the pressure is [Pi] dynes per square centimetre, and e the charge in
electrostatic units. This relation is obtained on the hypothesis that
N ions in a cubic centimetre produce the same pressure as N uncharged
molecules.
We know the value of D from Townsend's experiments and the values of u
from those of Zeleny. We get the following values for Ne × 10^-10:--
+---------------+---------------------+---------------------+
| | Moist Gas. | Moist Gas. |
+---------------+----------+----------+----------+----------+
| Gas. | Positive | Negative | Positive | Negative |
| | Ions. | Ions. | Ions. | Ions. |
+---------------+----------+----------+----------+----------+
| Air | 1.28 | 1.29 | 1.46 | 1.31 |
| Oxygen | 1.34 | 1.27 | 1.63 | 1.36 |
| Carbonic acid | 1.01 | .87 | .99 | .93 |
| Hydrogen | 1.24 | 1.18 | 1.63 | 1.25 |
+---------------+----------+----------+----------+----------+
| Mean | 1.22 | 1.15 | 1.43 | 1.21 |
+---------------+----------+----------+----------+----------+
Since 1.22 cubic centimetres of hydrogen at the temperature 15° C. and
pressure 760 mm. of mercury are liberated by the passage through
acidulated water of one electromagnetic unit of electricity or 3 ×
10^10 electrostatic units, and since in one cubic centimetre of the
gas there are 2.46 N atoms of hydrogen, we have, if E is the charge in
electrostatic units, on the atom of hydrogen in the electrolysis of
solutions
2.46NE = 3 × 10^10,
or
NE = 1.22 × 10^10.
Public-domain text, read in full here on John Shaqi.
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