The first discoveries in this field were made in the last quarter of the
18th century by J.B. Richter. The point at issue was a rather
commonplace one: it was the fact that when two neutral salt solutions
were mixed to undergo mutual chemical decomposition and recombination,
the resulting liquid was neutral again, i.e. it did not contain any
excess of acid or base. In other words, if two salts, A'B' and A" B",
composed of the acids A' and A" and the bases B' and B", undergo mutual
decomposition, the amount of the base B' left by the first salt, when
its acid A' united with the base B" to form a new salt A'B", was just
enough to make a neutral salt A"B' with the acid A" left by the second
salt. At first sight this looks quite simple and self-evident,--that
neutral salts should form neutral ones again and not acid or basic
ones,--but if this fact is once stated very serious quantitative
inferences may be drawn from it, as Richter showed. For if the symbols
A', A", B', B" denote at the same time such quantities of the acids and
bases as form neutral salts, then if three of these quantities are
determined, the fourth may be calculated from the others. This follows
from the fact that by decomposing A'B' with just the proper amount of
the other salt to form A'B", the remaining quantities B' and A" exist in
exactly the ratio to form a neutral salt A" B'. It is possible,
therefore, to ascribe to each acid and base a certain relative weight or
"combining weight" by which they will combine one with the other to form
neutral salts. The same reasoning may be extended to any number of acids
and bases.
It is true that Richter did not find out by himself this simplest
statement of the law of neutrality which he discovered, but he expressed
the same consequence in a rather clumsy way by a table of the combining
weights of different bases related to the unit amount of a certain acid,
and doing the same thing for the unit weight of every other acid. Then
he observed that the numbers in these different tables are proportionate
one to another. The same holds good if the corresponding series of the
combining weights of acids for unit weights of different bases were
tabulated. It was only a little later that a Berlin physicist, G.E.
Fischer, united the whole system of Richter's numbers simply into a
double table of acids and bases, taking as unit an arbitrarily chosen
substance, namely sulphuric acid. The following table by Fischer is
therefore the first table of combining weights.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account