in which oxygen and hydrogen combine to form water, we determine in this
way also the relative weight of their atoms. By a proper number of
analyses of simple chemical compounds we may determine the ratios
between the weights of all elementary atoms, and, selecting one of them
as a standard or unit, we may express the weight of all other atoms in
terms of this unit. The following table is Dalton's (_Mem. of the Lit.
and Phil. Soc. of Manchester_ (II.), vol. i. p. 287, 1805).
_Table of the Relative Weights of the Ultimate Particles of Gaseous
and other Bodies._
Hydrogen 1 | Nitrous oxide 13.7
Azot 4.2 | Sulphur 14.4
Carbone 4.3 | Nitric acid 15.2
Ammonia 5.2 | Sulphuretted hydrogen 15.4
Oxygen 5.5 | Carbonic acid 15.3
Water 6.5 | Alcohol 15.1
Phosphorus 7.2 | Sulphureous acid 19.9
Phosphuretted hydrogen 8.2 | Sulphuric acid 25.4
Nitrous gas 9.3 | Carburetted hydrogen from
Ether 9.6 | stagnant water 6.3
Gaseous oxide of carbone 9.8 | Olefiant gas 5.3
Dalton at once drew a peculiar inference from this view. If two elements
combine in different ratios, one must conclude that different numbers of
atoms unite. There must be, therefore, a simple ratio between the
quantities of the one element united to the same quantity of the other.
Dalton showed at once that the analysis of carbon monoxide and of
carbonic acid satisfied this consequence, the quantity of oxygen in the
second compound being double the quantity in the first one. A similar
relation holds good between marsh gas and olefiant gas (ethylene). This
is the "law of multiple proportions" (see ATOM). By these considerations
Dalton extended the law of combining weights, which Richter had
demonstrated only for neutral salts, to all possible chemical compounds.
While the scope of the law was enormously extended, its experimental
foundation was even smaller than with Richter. Dalton did not concern
himself very much with the experimental verification of his ideas, and
the first communication of his theory in a paper on the absorption of
gases by liquids (1803) attracted as little notice as Richter's
discoveries. Even when T. Thomson published Dalton's views in an
appendix to his widely read text-book of chemistry, matters did not
change very much. It was only by the work of J.J. Berzelius that the
enormous importance of Dalton's views was brought to light.
Work of J.J. Berzelius.
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