Berzelius was at that time busy in developing a trustworthy system of
chemical analysis, and for this purpose he investigated the composition
of the most important salts. He then went over the work of Richter, and
realized that by his law he could check the results of his analyses. He
tried it and found the law to hold good in most cases; when it did not,
according to his analyses, he found that the error was on his own side
and that better analyses fitted Richter's law. Thus he was prepared to
understand the importance of Dalton's views and he proceeded at once to
test its exactness. The result was the best possible. The law of the
combining weights of the atoms, or of the atomic weights, proved to
hold good in every case in which it was tested. All chemical
combinations between the several elements are therefore regulated by
weight according to certain numbers, one for each element, and
combinations between the elements occur only in ratios given by these
weights or by simple multiples thereof. Consequently Berzelius regarded
Dalton's atomic hypothesis as proved by experiment, and became a strong
believer in it.
At the same time W.H. Wollaston had discovered independently the law of
multiple proportions in the case of neutral and acid salts. He gave up
further work when he learned of Dalton's ideas, but afterwards he
pointed out that it was necessary to distinguish the _hypothetical_ part
in Dalton's views from their _empirical_ part. The latter is the law of
combining weights, or the law that chemical combination occurs only
according to certain numbers characteristic for each element. Besides
this purely experimental law there is the hypothetical explanation by
the assumption of the existence of atoms. As it is not proved that this
explanation is the only one possible, the existence of the law is not a
proof of the existence of the atoms. He therefore preferred to call the
characteristic combining numbers of the elements not "atomic weights"
but "chemical equivalents."
Although there were at all times chemists who shared Wollaston's
cautious views, the atomic hypothesis found general acceptance because
of its ready adaptability to the most diverse chemical facts. In our
time it is even rather difficult to separate, as Wollaston did, the
empirical part from the hypothetical one, and the concept of the atom
penetrates the whole system of chemistry, especially organic chemistry.
Public-domain text, read in full here on John Shaqi.
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