Experimentally this important fact was proved first by Berzelius, who
showed that by oxidizing lead sulphide, PbS, to lead sulphate, PbSO4, no
excess either of sulphur or lead could be found after oxidation; the
same held good with barium sulphite, BaSO3, when converted into barium
sulphate, BaSO4. On a much larger scale and with very great accuracy
the inverse was proved half a century later by J.S. Stas, who reduced
silver chlorate, AgClO3, silver bromate, AgBrO3, and silver iodate,
AgIO3, to the corresponding binary compounds, AgCl, AgBr and AgI, and
searched in the residue of the reaction for any excess of silver or
halogen. As the tests for these substances are among the most sensitive
in analytical chemistry, the general law underwent a very severe test
indeed. But the result was the same as was found by Berzelius--no excess
of one of the elements could be discovered. We may infer, therefore,
generally that compounds enter ulterior combinations without change of
the ratio of their elements, or that the ratio between different
elements in their compounds is the same in binary and ternary (or still
more complicated) combinations.
This law involves the existence of general combining weights just in the
same way as the law of neutrality with double decomposition of salts
involves the law of the combining weights of acids and bases. For if the
ratio between A and B is determined, this same ratio must obtain in all
ternary and more complicated compounds, containing the same elements.
The same is true for any other elements, C, D, E, F, &c., as related to
A. But by applying the general law to the ternary compound ABC the same
conclusion may be drawn as to the ratio A : C in all compounds
containing A and C, or B : C in the corresponding compounds. By
reasoning further in the same way, we come to the conclusion that only
such compounds are possible which contain elements according to certain
ratio-numbers, i.e. their combining weight. Any other ratio would
violate the law of the integral reaction of compounds.
As to the law of multiple proportions, it may be deduced by a similar
reasoning by considering the possible combinations between a compound,
e.g. AB, and one of its elements, say B. AB and B can combine only
according to their combining weights, and therefore the quantity of B
combining with AB is equal to the quantity of AB which has combined with
A to form AB. The new combination is therefore to be expressed by AB2.
By extending this reasoning in the same way, we get the general
conclusion that any compounds must be composed according to the formula
A_m B_n C_p..., where m, n, p, &c., are integers.
Public-domain text, read in full here on John Shaqi.
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