The bearing of these considerations on the atomic hypothesis is not to
disprove it, but rather to show that the existence of the law of
combining weights, which has been considered for so long as a proof of
the truth of this hypothesis, does not necessarily involve such a
consequence. Whether atoms may prove to exist or not, the law of
combining weights is independent thereof.
Atomic weight determinations.
Two problems arose from the discoveries of Dalton and Berzelius. The
first was to determine as exactly as possible the correct numbers of the
combining weights. The other results from the fact that the same
elements may combine in different ratios. Which of these ratios gives
the true ratio of the atomic weights? And which is the multiple one?
Both questions have had most ample experimental investigation, and are
now answered rather satisfactorily. The first question was a purely
technical one; its answer depended upon analytical skill, and Berzelius
in his time easily took the lead, his numbers being readily accepted on
the continent of Europe. In England there was a certain hesitation at
first, owing to Prout's assumption (see below), but when Turner, at the
instigation of the British Association for the Advancement of Science,
tested Berzelius's numbers and found them entirely in accordance with
his own measurements, these numbers were universally accepted. But then
a rather large error in one of Berzelius's numbers (for carbon) was
discovered in 1841 by Dumas and Stas, and a kind of panic ensued. New
determinations of the atomic weights were undertaken from all sides. The
result was most satisfactory for Berzelius, for no other important error
was discovered, and even Dumas remarked that repeating a determination
by Berzelius only meant getting the same result, if one worked properly.
In later times more exact measurements, corresponding to the increasing
art in analysis, were carried out by various workers, amongst whom J.S.
Stas distinguished himself. But even the classical work of Stas proved
not to be entirely without error; for every period has its limit in
accuracy, which extends slowly as science extends. In recent times
American chemists have been especially prominent in work of this kind,
and the determinations of E.W. Morley, T.W. Richards and G.P. Baxter
rank among the first in this line of investigation.
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