_The Periodic Law._--The history of this discovery is rather long. As
early as 1817 J.W. Döbereiner of Jena drew attention to the fact that
the combining weight of strontium lies midway between those of calcium
and barium, and some years later he showed that such "triads" occurred
in other cases too. L. Gmelin tried to apply this idea to all elements,
but he realized that in many cases more than three elements had to be
grouped together. While Ernst Lenssen applied the idea of triads to the
whole table of chemical elements, but without any important result, the
other idea of grouping more than three elements into series according to
their combining weights proved more successful. It was the concept of
homologous series just developed in organic chemistry which influenced
such considerations. First Max von Pettenkofer in 1850 and then J.B.A.
Dumas in 1851 undertook to show that such a series of similar elements
could be formed, having nearly constant differences between their
combining weights. It is true that this idea in all its simplicity did
not hold good extensively enough; so J.P. Cooke and Dumas tried more
complicated types of numerical series, but only with a temporary
success.
The idea of arranging all elements in a single series in the order of
the magnitude of their combining weights, the germ of which is to be
found already in J.B. Richter's work, appears first in 1860 in some
tables published by Lothar Meyer for his lectures. Independently, A.E.B.
de Chancourtois in 1862, J.A.R. Newlands in 1863, and D.I. Mendeléeff in
1869, developed the same idea with the same result, namely, that it is
possible to divide this series of all the elements into a certain number
of very similar parts. In their papers, which appeared in the same year,
1869, Lothar Meyer and Mendeléeff gave to all these trials the shape now
generally adopted. They succeeded in proving beyond all doubt that this
series was of a _periodic character_, and could be cut into shorter
pieces of similar construction. Here again gaps were present to be
filled up by elements to be discovered, and Mendeléeff, who did this,
predicted from the general regularity of his table the properties of
such unknown elements. In this case fate was more kind than with
Richter, and science had the satisfaction of seeing these predictions
turn out to be true.
The following table contains this periodic arrangement of the elements
according to their atomic weight. By cutting the whole series into
pieces of eight elements (or more in several cases) and arranging these
one below another in the alternating way shown in the table, one finds
similar elements placed in vertical series whose properties change
gradually and with some regularity according to their place in the
table. Not only the properties of the uncombined elements obey this
rule, but also almost all properties of similar compounds of the
elements.
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