These experiments apparently suggested a small decrease of weight as a
consequence of chemical processes. On repeating them, however, and
making allowance for the different amounts of water absorbed on the
surface of the vessel at the beginning and end of the experiment,
Landolt found in 1908 (_Zeit. physik. Chem._ 64, p. 581) that the
variations in weight are equally positive and negative, and he concluded
that there was no change in weight, at least to the extent of 1 part in
10,000,000.
The periodic arrangement.
There is still another question regarding the numerical values of the
atomic weights, namely: Are there relations between the numbers
belonging to the several elements? Richter had arranged his combining
weights according to their magnitude, and endeavoured to prove that they
form a certain mathematical series. He also explained the incompleteness
of his series by assuming that certain acids or bases requisite to the
filling up of the gaps in the series, were not yet known. He even had
the satisfaction that in his time a new base was discovered, which
fitted rather well into one of his gaps; but when it turned out
afterwards that this new base was only calcium phosphate, this way of
reasoning fell into discredit and was resumed only at a much later date.
To obtain a correct table of atomic weights the second question already
mentioned, viz. how to select the correct value in the case of multiple
proportions, had to be answered. Berzelius was constantly on the
look-out for means to distinguish the true atomic weights from their
multiples or sub-multiples, but he could not find an unmistakable test.
The whole question fell into a terrible disorder, until in the middle of
the 19th century S. Cannizzaro showed that by taking together all
partial evidences one could get a system of atomic weights consistent in
itself and fitting the exigencies of chemical systematics. Then a
startling discovery was made by the same method which Richter had tried
in vain, by arranging all atomic weights in one series according to
their numerical values.
Public-domain text, read in full here on John Shaqi.
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