2. _The Change of State of Matter._--By a change of temperature and
pressure combined, a substance can in general be made to pass from one
state into another; thus by gradually increasing the temperature a solid
piece of ice can be melted into the liquid state of water, and the water
again can be boiled off into the gaseous state as steam. Again, by
raising the temperature, a metal in the solid state can be melted and
liquefied, and poured into a mould to assume any form desired, which is
retained when the metal cools and solidifies again; the gaseous state of
a metal is revealed by the spectroscope. Conversely, a combination of
increased pressure and lowering of temperature will, if carried far
enough, reduce a gas to a liquid, and afterwards to the solid state; and
nearly every gaseous substance has now undergone this operation.
A certain critical temperature is observed in a gas, above which the
liquefaction is impossible; so that the gaseous state has two
subdivisions into (i.) a true gas, which cannot be liquefied, because
its temperature is above the critical temperature, (ii.) a vapour, where
the temperature is below the critical, and which can ultimately be
liquefied by further lowering of temperature or increase of pressure.
3. _Plasticity and Viscosity._--Every solid substance is found to be
plastic more or less, as exemplified by punching, shearing and cutting;
but the plastic solid is distinguished from the viscous fluid in that a
plastic solid requires a certain magnitude of stress to be exceeded to
make it flow, whereas the viscous liquid will yield to the slightest
stress, but requires a certain length of time for the effect to be
appreciable.
According to Maxwell (_Theory of Heat_) "When a continuous alteration of
form is produced only by a stress exceeding a certain value, the
substance is called a solid, however soft and plastic it may be. But
when the smallest stress, if only continued long enough, will cause a
perceptible and increasing change of form, the substance must be
regarded as a viscous fluid, however hard it may be." Maxwell
illustrates the difference between a soft solid and a hard liquid by a
jelly and a block of pitch; also by the experiment of supporting a
candle and a stick of sealing-wax; after a considerable time the
sealing-wax will be found bent and so is a fluid, but the candle remains
straight as a solid.
4. _Definition of a Fluid._--A fluid is a substance which yields
continually to the slightest tangential stress in its interior; that is,
it can be divided very easily along any plane (given plenty of time if
the fluid is viscous). It follows that when the fluid has come to rest,
the tangential stress in any plane in its interior must vanish, and the
stress must be entirely normal to the plane. This mechanical axiom of
the _normality of fluid pressure_ is the foundation of the mathematical
theory of hydrostatics.
Public-domain text, read in full here on John Shaqi.
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