| Mercury |14.382 | .. | 0.0000881**|
| Sodium | 1.0056 | 0.972 | 0.0001810 |
| Graphite (Cumberland) | 2.1302 | 2.0990 | 0.0000733 |
+---------------------------+---------+--------+------------+
* The figures within parentheses refer to the number of molecules of
water of crystallization.
** -189° to -38.85° C.
It will be seen from this table that, with the exception of carbonate
of soda and chrome alum, the hydrated salts have a coefficient of
expansion that does not differ greatly from that of ice at low
temperatures. Iodoform is a highly expansive body like iodine, and
oxalate of methyl has nearly as great a coefficient as paraffin, which
is a very expansive solid, as are naphthalene and oxalic acid. The
coefficient of solid mercury is about half that of the liquid metal,
while that of sodium is about the value of mercury at ordinary
temperatures. Further details on the subject can be found in the
_Proc. Roy. Inst._ (1895), and _Proc. Roy. Soc._ (1902).
_Density of Gases at Low Temperatures._--The ordinary mode of
determining the density of gases may be followed, provided that the
glass flask, with its carefully ground stop-cock sealed on, can stand
an internal pressure of about five atmospheres, and that all the
necessary corrections for change of volume are made. All that is
necessary is to immerse the exhausted flask in boiling oxygen, and
then to allow the second gas to enter from a gasometer by opening the
stop-cock until the pressure is equalized. The stop-cock being closed,
the flask is now taken out of the liquid oxygen and left in the
balance-room until its temperature is equalized. It is then weighed
against a similar flask used as a counterpoise. Following such a
method, it has been found that the weight of 1 litre of oxygen vapour
at its boiling point of 90.5° absolute is 4.420 grammes, and therefore
the specific volume is 226.25 cc. According to the ordinary gaseous
laws, the litre ought to weigh 4.313 grammes, and the specific volume
should be 231.82 cc. In other words, the product of pressure and
volume at the boiling point is diminished by 2.46%. In a similar way
the weight of a litre of nitrogen vapour at the boiling point of
oxygen was found to be 3.90, and the inferred value for 78° absolute,
or its own boiling point, would be 4.51, giving a specific volume of
221.3.
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