_Gas Absorption by Charcoal._--Felix Fontana was apparently the first to
discover that hot charcoal has the power of absorbing gases, and his
observations were confirmed about 1770 by Joseph Priestley, to whom he
had communicated them. A generation later Theodore de Saussure made a
number of experiments on the subject, and noted that at ordinary
temperatures the absorption is accompanied with considerable evolution
of heat. Among subsequent investigators were Thomas Graham and
Stenhouse, Faure and Silberman, and Hunter, the last-named showing that
charcoal made from coco-nut exhibits greater absorptive powers than
other varieties. In 1874 Tait and Dewar for the first time employed
charcoal for the production of high vacua, by using it, heated to a red
heat, to absorb the mercury vapour in a tube exhausted by a mercury
pump; and thirty years afterwards it occurred to the latter investigator
to try how its absorbing powers are affected by cooling it, with the
result that he found them to be greatly enhanced. Some of his earlier
observations are given in table III., but it must be pointed out that
much larger absorptions were obtained subsequently when it was found
that the quality of the charcoal was greatly influenced by the mode in
which it was prepared, the absorptive power being increased by
carbonizing the coco-nut shell slowly at a gradually increasing
temperature. The results in the table were all obtained with the same
specimen of charcoal, and the volumes of the gases absorbed, both at
ordinary and at low temperatures, were measured under standard
conditions--at 0° C., and 760 mm. pressure. It appears that at the lower
temperature there is a remarkable increase of absorption for every gas,
but that the increase is in general smaller as the boiling-points of the
various gases are lower. Helium is conspicuous for the fact that it is
absorbed to a comparatively slight extent at both the higher and the
lower temperature, but in this connexion it must be remembered that,
being the most volatile gas known, it is being treated at a temperature
which is relatively much higher than the other gases. At -185° (= 88°
abs.), while hydrogen is at about 4½ times its boiling-point (20° abs.),
helium is at about 20 times its boiling-point (4.5° abs.), and it might,
therefore, be expected that if it were taken at a temperature
corresponding to that of the hydrogen, i.e. at 4 or 5 times its
boiling-point, or say 20° abs., it would undergo much greater
absorption. This expectation is borne out by the results shown in table
IV., and it may be inferred that charcoal cooled in liquid helium would
absorb helium as freely as charcoal cooled in liquid hydrogen absorbs
hydrogen. It is found that a given specimen of charcoal cooled in liquid
oxygen, nitrogen and hydrogen absorbs about equal volumes of those three
gases (about 260 cc. per gramme); and, as the relation between volume
and temperature is nearly lineal at the lowest portions of either the
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