_Production of High Vacua._--Exceedingly high vacua can be obtained by
the aid of liquid gases, with or without charcoal. If a vessel
containing liquid hydrogen be freely exposed to the atmosphere, a rain
of snow (solid air) at once begins to fall upon the surface of the
liquid; similarly, if one end of a sealed tube containing ordinary air
be immersed in the liquid, the same thing happens, but since there is
now no new supply to take the place of the air that has been solidified
and has accumulated in the cooled portion of the tube, the pressure is
quickly reduced to something like one-millionth of an atmosphere, and a
vacuum is formed of such tenuity that the electric discharge can be made
to pass only with difficulty. Liquid air can be employed in the same
manner if the tube, before sealing, is filled with some less volatile
gas or vapour, such as sulphurous acid, benzol or water vapour. But if a
charcoal condenser be used in conjunction with the liquid air it becomes
possible to obtain a high vacuum when the tube contains air initially.
For instance, in one experiment, with a bulb having a capacity of 300
cc. and filled with air at a pressure of about 1.7 mm. and at a
temperature of 15° C., when an attached condenser with 5 grammes of
charcoal was cooled in liquid air, the pressure was reduced to 0.0545
mm. of mercury in five minutes, to 0.01032 mm. in ten minutes, to
0.000139 mm. in thirty minutes, and to 0.000047 mm. in sixty minutes.
The condenser then being cooled in liquid hydrogen the pressure fell to
0.0000154 mm. in ten minutes, and to 0.0000058 mm. in a further ten
minutes when solid hydrogen was employed as the cooling agent, and no
doubt, had it not been for the presence of hydrogen and helium in the
air, an even greater reduction could have been effected. Another
illustration of the power of cooled charcoal to produce high vacua is
afforded by a Crookes radiometer. If the instrument be filled with
helium at atmospheric pressure and a charcoal bulb attached to it be
cooled in liquid air, the vanes remain motionless even when exposed to
the concentrated beam of an electric arc lamp; but if liquid hydrogen be
substituted for the liquid air rapid rotation at once sets in. When a
similar radiometer was filled with hydrogen and the attached charcoal
bulb was cooled in liquid air rotation took place, because sufficient of
the gas was absorbed to permit motion. But when the charcoal was cooled
in liquid hydrogen instead of in liquid air, the absorption increased
and consequently the rarefaction became so high that there was no motion
when the light from the arc was directed on the vanes. These experiments
again permit of an inference as to the boiling-point of helium. A fall
of 75% in the temperature of the charcoal bulb, from the boiling-point
of air to the boiling-point of hydrogen, reduced the vanes to rest in
the case of the radiometer filled with hydrogen; hence it might be
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