_Phosphorescence._--Phosphorescing sulphides of calcium, which are
luminous at ordinary temperatures, and whose emission of light is
increased by heating, cease to be luminous if cooled to -80° C. But
their light energy is merely rendered latent, not destroyed, by such
cold, and they still retain the capacity of taking in light energy at
the low temperature, to be evolved again when they are warmed. At the
temperature of liquid air many bodies become phosphorescent which do not
exhibit the phenomenon at all, or only to a very slight extent, at
ordinary temperatures, e.g. ivory, indiarubber, egg-shells, feathers,
cottonwool, paper, milk, gelatine, white of egg, &c. Of definite
chemical compounds, the platinocyanides among the inorganic bodies seem
to yield the most brilliant effects. Crystals of ammonium
platinocyanide, if stimulated by exposure to the ultra-violet radiation
of the electric arc--or better still of a mercury vapour lamp in
quartz--while kept moistened with liquid air, may be seen in the dark to
glow faintly so long as they are kept cold, but become exceedingly
brilliant when the liquid air evaporates and the temperature rises.
Among organic bodies the phenomenon is particularly well marked with the
ketonic compounds and others of the same type. The chloro-, bromo-,
iodo-, sulpho- and nitro-compounds show very little effect as a rule.
The activity of the alcohols, which is usually considerable, is
destroyed by the addition of a little iodine. Coloured salts, &c., are
mostly inferior in activity to white ones. When the lower temperature of
liquid hydrogen is employed there is a great increase in phosphorescence
under light stimulation as compared with that observed with liquid air.
The radio-active bodies, like radium, which exhibit self-luminosity in
the dark, maintain that luminosity unimpaired when cooled in liquid
hydrogen.
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