_Electrical Resistivity._--The first experiments on the conductivity of
metals at low temperatures appear to have been made by Wroblewski
(_Comptes rendus_, ci. 160), and by Cailletet and Bouty (_Journ. de
phys._ 1885, p. 297). The former's experiments were undertaken to test
the suggestion made by Clausius that the resistivity of pure metals is
sensibly proportional to the absolute temperature; he worked with copper
having a conductibility of 98%, and carried out measurements at various
temperatures, the lowest of which was that given by liquid nitrogen
boiling under reduced pressure. His general conclusion was that the
resistivity decreases much more quickly than the absolute temperature,
so as to approach zero at a point not far below the temperature of
nitrogen evaporating _in vacuo_. Cailletet and Bouty, using ethylene as
the refrigerant, and experimenting at temperatures ranging from 0° C. to
-100° C. and -123° C., constructed formulae intended to give the
coefficients of variation in electrical resistance for mercury, tin,
silver, magnesium, aluminium, copper, iron and platinum. Between 1892
and 1896 Dewar and Fleming carried out a large number of experiments to
ascertain the changes of conductivity that occur in metals and alloys
cooled in liquid air or oxygen to -200° C. The method employed was to
obtain the material under investigation in the form of a fine regular
wire and to wind it in a small coil; this was then plunged in the liquid
and its resistance determined. The accompanying chart (fig. 14) gives
the results in a compendious form, the temperatures being expressed not
in degrees of the ordinary air-thermometer scale, but in platinum
degrees as given by one particular platinum resistance thermometer which
was used throughout the investigation. A table showing the value of
these degrees in degrees centigrade according to Dickson will be found
in the _Phil. Mag._ for June 1898, p. 527; to give some idea of the
relationship, it may be stated here that -100° of the platinum
thermometer = -94°.2 C., -150° plat. = -140°.78 C., and -200° plat. =
-185°.53 C. In general, the resistance of perfectly pure metals was
greatly decreased by cold--so much so that, to judge by the course of
the curves on the chart, it appeared probable that at the zero of
absolute temperature resistance would vanish altogether and all pure
metals become perfect conductors of electricity. This conclusion,
however, has been rendered very doubtful by subsequent observations by
Dewar, who found that with the still lower temperatures attainable with
liquid hydrogen the increases of conductivity became less for each
decrease of temperature, until a point was reached where the curves bent
sharply round and any further diminution of resistance became very
small; that is, the conductivity remained finite. The reduction in
resistance of some of the metals at the boiling point of hydrogen is
very remarkable. Thus copper has only (1/105)th, gold (1/30)th, platinum
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